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Heterobimetallic Cyclosiloxanolate Sandwich Clusters: Na[η6-cyclo(PhSiO2)6]2[Fe(OR)]2Ni4(μ6-Cl) (R = H, Me)

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Abstract

The heterobimetallic cyclosiloxanolate sandwich clusters Na[η6-cyclo (PhSiO2)6]2[Fe(OR)]2Ni4(μ6-Cl) (R = H, Me) (1) were prepared from Na2[(PhSiO2)6]2Na4Ni4(OH)2 in the form of solvates. The new clusters 1 were characterized by spectra (UV-VIS, IR, 1H-NMR), cyclic voltammetry. conductivity, magnetic susceptibility, and single-crystal X-ray diffraction.

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Authors and Affiliations

  1. Department of Chemistry, University of Modena, Via Campi 183, I-41100, Modena, Italy

    A. Cornia, A. C. Fabretti, G. Gavioli, C. Zucchi & G. Pályi

  2. Department of Inorganic and Organometallic Chemistry and CNR Center, University of Milano, Via Venezian 21, I-20113, Milano, Italy

    M. Pizzotti

  3. Research Group for Petrochemistry, Hungarian Academy of Sciences, Egyetem-u. 8, H-8200, Veszprém, Hungary

    A. Vizi-Orosz

  4. A.N. Nesmeyanov Institute of Organoelement Chemistry, Russian Academy of Sciences, 28 Vavilov Street, Moscow, 117813, Russia

    O. I. Shchegolikhina & Yu. A. Pozdniakova

  5. Work partly done at the University of Modena, Italy

    O. I. Shchegolikhina

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  1. A. Cornia
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Cornia, A., Fabretti, A.C., Gavioli, G. et al. Heterobimetallic Cyclosiloxanolate Sandwich Clusters: Na[η6-cyclo(PhSiO2)6]2[Fe(OR)]2Ni4(μ6-Cl) (R = H, Me). Journal of Cluster Science 9, 295–319 (1998). https://doi.org/10.1023/A:1022631127705

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