Abstract
Densities for DMSO solutions of divalent transition metal perchlorates are reported. The partial molar volumes of the hexakis-(DMSO) cations are derived and discussed in terms of variation within the \({\text{M}}^{{\text{2 + }}} - {\text{Zn}}^{{\text{2 + }}}\) series. The ligand-field effect on the partial molar volume and enthalpy of solvation is demonstrated.
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REFERENCES
W. Libuś, B. Chachulski, W. Grzybkowski, M. Pilarczyk, and D. Puchalska, J. Solution Chem. 10, 631 (1981).
W. Grzybkowski and M. Pilarczyk, J. Chem. Soc. Faraday Trans. I, 79, 2319 (1983).
W. Grzybkowski, Polyhedron 9, 2257 (1990).
S. F. Lincoln, A. M. Hounslow, and A. N. Boffa, Inorg. Chem. 25, 1038 (1986).
W. Grzybkowski and M. Pilarczyk, Electrochim. Acta 32, 1601 (1987).
Y. Abe and G. Wada, Bull. Chem. Soc. Jpn., 53, 3547 (1980).
W. Grzybkowski, M. Pilarczyk, and L. Klinszporn, J. Chem. Soc. Faraday Trans. I, 84, 1551 (1988).
W. Libuś, W. Grzybkowski, and R. Pastewski, J. Chem. Soc., Faraday Trans. I, 77, 147 (1981).
Libuś and R. Pastewski, J. Solution Chem. 17, 59 (1988).
G. S. Kell, J. Chem. Eng. Data 12, 66 (1967).
W. Grzybkowski and R. Pastewski, Electrochim. Acta 25, 279 (1980).
Ch. Atlani and J. C. Justice, J. Solution Chem., 4, 955 (1975).
K. M. Kale and R. Zana, J. Solution Chem. 6, 733 (1977).
S. J. Romanowski, C. M. Kinart, and W. J. Kinart, J. Chem. Soc. Faraday Trans. 91, 65 (1989).
F. J. Millero, Chem. Rev. 71, 147 (1971).
O. Redlich and P. Rosenfeld, Z. Electrochem. 37, 105 (1931).
K. S. Pitzer, Activity Coefficients in Electrolyte Solutions, 2nd edn. (CRC Press, Boca Raton, Florida, 1991).
B. E. Conway, J. Solution Chem. 7, 721 (1978).
F. J. Millero, in Water and Aqueous Solutions, R. A. Horne, ed., (Wiley, New York, 1972).
W. Libuś M. Męcik, and H. Strzelecki, J. Solution Chem. 9, 723 (1980).
L. E. Orgel, J. Chem. Soc., p. 4756 (1952).
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Bobicz, D., Grzybkowski, W. Apparent Molar Volumes of Divalent Transition Metal Cations in Dimethyl Sulfoxide Solutions. Journal of Solution Chemistry 27, 817–826 (1998). https://doi.org/10.1023/A:1022629203906
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DOI: https://doi.org/10.1023/A:1022629203906