Abstract
Previous applications of the Flory–Patterson theory in the analysis of the excess molar enthalpies at 25°C for some binary mixtures composed of ethers, n-alkanes, br-alknes, and cycloalkanes are reviewed. The possibility of correlating the Flory interaction parameters X ij in terms of the acentric factors of the components is examined. For selected ether (1) + n-alkane(2) mixtures, a set of linear relations between X 12 and the acentric factors of the n-alkanes are reported.
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Peng, DY., Benson, G.C. & Lu, B.CY. Predicting Excess Enthalpies of Ether and/or Hydrocarbon Binary Mixtures. Journal of Solution Chemistry 28, 505–519 (1999). https://doi.org/10.1023/A:1022626830834
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DOI: https://doi.org/10.1023/A:1022626830834