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Metal–Carbonyl Clusters with Alkynes Bound in “Parallel” or “Perpendicular” Fashion

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Abstract

Alkyne-substituted tri- and polynuclear clusters have been known for a long time. Among these, the derivatives with acetylene substituents coordinated parallel to one edge of a trimetallic cluster represent the majority. Clusters with alkynes perpendicular to one edge of a trimetallic cluster are not very common. The reactivity of these clusters is discussed in this paper; particular attention is devoted to the chemical transformations which could occur during catalytic reactions. Some examples of the behavior of these clusters in homogeneous and solid–gas hydrogenation catalysis are given.

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  1. Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali, Universitá di Torino, Via Pietro Giuria 7, I-10125, Torino, Italy

    Stefano Deabate, Roberto Giordano & Enrico Sappa

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  1. Stefano Deabate
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Deabate, S., Giordano, R. & Sappa, E. Metal–Carbonyl Clusters with Alkynes Bound in “Parallel” or “Perpendicular” Fashion. Journal of Cluster Science 8, 407–459 (1997). https://doi.org/10.1023/A:1022622728887

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