Publications of Kenneth S. Pitzer
Journals and Book Chapters
P. P. S. Saluja, K. S. Pitzer, and R. C. Phutela, “High-Temperature Thermodynamic Properties of Several 1:1 Electrolytes,” Can. J. Chem. 64, 1328–1335 (1986).
J. M. H. Levelt Sengers, C. M. Everhart, G. Morrison, and K. S. Pitzer, “Thermodynamic Anomalies in Near-Critical Aqueous NaCl Solutions,” Chem. Eng. Commun. 47, 315–328 (1986).
K. S. Pitzer, “Thermodynamic Properties of Ionic Fluids Over Wide Ranges of Temperature,” Pure Appl. Chem. 59, 1–6 (1987).
R. C. Phutela, K. S. Pitzer, and P. P. S. Saluja, “Thermodynamics of Aqueous Magnesium Chloride, Calcium Chloride, and Strontium Chloride at Elevated Temperatures,” J. Chem. Eng. Data 32, 76–80 (1987).
K. Balasubramanian and K. S. Pitzer, “Relativistic Quantum Chemistry,” in Ab Initio Methods in Quantum Chemistry, Vol. I, K. P. Lawley, ed. (Wiley Interscience, New York, 1987), pp. 287–319.
R. P. Neisler and K. S. Pitzer, “The Dipositive Dimeric Ion Hg2 2+: A Theoretical Study,” J. Phys. Chem. 91, 1084–1087 (1987).
K. S. Pitzer, J. L. Bischoff, and R. J. Rosenbauer, “Critical Behavior of Dilute NaCl in H2O,” Chem. Phys. Lett. 134, 60–63 (1987).
K. S. Pitzer and D. R. Schreiber, “The Restricted Primitive Model for Ionic Fluids. Properties of the Vapor and the Critical Region,” Mol. Phys. 60, 1067–1078 (1987).
R. T. Pabalan and K. S. Pitzer, “Thermodynamics of NaOH(aq) in Hydrothermal Solutions,” Geochim. Cosmochim. Acta 51, 829–837 (1987).
D. R. Schreiber, M. C. P. de Lima, and K. S. Pitzer, “Electrical Conductivity, Viscosity, and Density of a Two-Component Ionic System at Its Critical Point,” J. Phys. Chem. 91, 4087–4091 (1987).
R. T. Pabalan and K. S. Pitzer, “Thermodynamics of Concentrated Electrolyte Mixtures and the Prediction of Mineral Solubilities to High Temperatures for Mixtures in the System Na-K-Mg-Cl-SO4-OH-H2O,” Geochim. Cosmochim. Acta 51, 2429–2443 (1987).
K. S. Pitzer, “A Thermodynamic Model for Aqueous Solutions of Liquid-Like Density,” in Reviews in Mineralogy, Vol. 17, Mineralogical Society of America, Chap. 4, I. S. E. Carmichael and H. P. Eugster, eds. (BookCrafters, Chelsea, MI, 1987).
K. S. Pitzer, “Of Physical Chemistry and Other Activities,” Annu. Rev. Phys. Chem. 38, 1–25 (1987).
K. S. Pitzer and D. R. Schreiber, “Improving Equation-of-State Accuracy in the Critical Region; Equations for Carbon Dioxide and Neopentane as Examples,” Fluid Phase Equil. 41, 1–17 (1988).
R. T. Pabalan and K. S. Pitzer, “Apparent Molar Heat Capacity and Other Thermodynamic Properties of Aqueous KCl Solutions to High Temperatures and Pressures,” J. Chem. Eng. Data 33, 354–362 (1988).
J.-Z. Yang and K. S. Pitzer, “Thermodynamics of Electrolyte Mixtures. Activity and Osmotic Coefficients Consistent with the Higher-Order Limiting Law for Symmetrical Mixing,” J. Solution Chem. 17, 909–924 (1988).
K. S. Pitzer and J. C. Tanger IV, “Near-Critical NaCl-H2O: An Equation of State and Discussion of Anomalous Properties,” Int. J. Thermophys. 9, 635–648 (1988).
D. R. Schreiber and K. S. Pitzer, “Selected Equation of State in the Acentric Factor System,” Int. J. Thermophys. 9, 965–974 (1988).
R. T. Pabalan and K. S. Pitzer, “Heat Capacity and Other Thermodynamic Properties of Na2SO4(aq) in Hydrothermal Solutions and the Solubilities of Sodium Sulfate Minerals in the System Na-Cl-SO4-OH-H2O to 300°C” Geochim. Cosmochim. Acta 52, 2393–2404 (1988).
R. R. Singh and K. S. Pitzer, “An Ionic System with Critical Point at 44°C, “J. Am. Chem. Soc. 110, 8723–8724 (1988).
J.-Z. Yang and K. S. Pitzer, “Thermodynamics of Aqueous Uranyl Sulfate to 559 K,” J. Solution Chem. 18, 189–199 (1989).
J. L. Bischoff and K. S. Pitzer, “Liquid-Vapor Relations for the System NaCl-H2O: Summary of the P-T-x Surface from 300° to 500°C,” Am. J. Sci. 289, 217–248 (1989).
K. S. Pitzer, “Some Interesting Properties of Vapor-Liquid or Liquid-Liquid Coexistence Curves for Ionic and Non-Ionic Fluids,” Thermochim. Acta 139, 25–32 (1989).
J.-Z. Yang and K. S. Pitzer, “The Application of the Ion-Interaction Model to Multicomponent 1–1 Type Electrolytes in Mixed Solvents,” J. Solution Chem. 18, 201–210 (1989).
K. S. Pitzer, “Fluids, Both Ionic and Nonionic, Over Wide Ranges of Temperature and Composition,” Pure Appl. Chem. 61, 979–988 (1989); also J. Chem. Thermodyn. 21, 1–17 (1989). (This is the text of the 1988 Rossini lecture.)
R. R. Singh and K. S. Pitzer, “Relationships in the Approach to Criticality in Fluids, Including Systematic Differences Between Vapor-Liquid and Liquid-Liquid Systems,” J. Chem. Phys. 90, 5742–5748 (1989).
K. S. Pitzer and J. C. Tanger IV, “Critical Exponents for the Coexistence Curves for NaCl-H2O Near the Critical Temperature of H2O. Reply to Comment by A. H. Harvey and J. M. H. Levelt Sengers,” Chem. Phys. Lett. 156, 418–419 (1989).
J. C. Tanger IV and K. S. Pitzer, “Calculation of the Thermodynamic Properties of Aqueous Electrolytes to 1000°C and 5000 bar from a Semicontinuum Model for Ion Hydration,” J. Phys. Chem. 93, 4941–4951 (1989).
J. C. Tanger IV and K. S. Pitzer, “Thermodynamics of NaCl-H2O: a New Equation of State for the Near-Critical Region and Comparisons with Other Equations for Adjoining Regions,” Geochim. Cosmochim. Acta 53, 973–987 (1989).
D. R. Schreiber and K. S. Pitzer, “Equation of State in the Acentric Factor System.” Fluid Phase Equil. 46, 113–130 (1989).
L. M. Connaughton, F. J. Millero, and K. S. Pitzer, “Volume Changes for Mixing the Major Sea Salts: Equations Valid to Ionic Strength 3.0 and Temperature 95°C,” J. Solution Chem. 18, 1007–1017 (1989).
J. C. Tanger IV and K. S. Pitzer, “Calculation of the Ionization Constant of H2O to 2273 K and 500 MPa,” AIChE J. 35, 1631–1638 (1989).
R. T. Pabalan and K. S. Pitzer, “Models for Aqueous Electrolyte Mixtures for Systems Extending from Dilute Solutions to Fused Salts,” in Chemical Modeling of Aqueous Systems II, ACS Symposium Series 416, Chap. 4, D. C. Melchior and R. L. Bassett, eds. (American Chemical Society, Washington, D.C., 1990).
J. K. Hovey, K. S. Pitzer, J. C. Tanger IV, J. L. Bischoff, and R. J. Rosenbauer, “Vapor-Liquid Phase Equilibria of Potassium Chloride-Water Mixtures: Equation-of-State Representation for KCl-H2O and NaCl-H2O,” J. Phys. Chem. 94, 1175–1179 (1990).
R. R. Singh and K. S. Pitzer, “Rectilinear Diameters and Extended Corresponding States Theory,” J. Chem. Phys. 92, 3096–3099 (1990).
R. T. Pabalan and K. S. Pitzer, “Prediction of High-Temperature Thermodynamic Properties of Mixed Electrolyte Solutions Including Solubility Equilibria, Vapor Pressure Depression and Boiling Point Elevation,” Proceedings of the 1987 Symposium on Chemistry in High-Temperature Water, Report EPRI NP-6005, Electric Power Research Institute, Palo Alto, CA, 1990.
R. R. Singh, K. S. Pitzer, J. J. de Pablo, and J. M. Prausnitz, “Monte Carlo Simulation of Phase Equilibria for the Two-Dimensional Lennard-Jones Fluid in the Gibbs Ensemble,” J. Chem. Phys. 92, 5463–5466 (1990).
R. R. Singh and K. S. Pitzer, “Near-Critical Coexistence Curve and Critical Exponent of an Ionic Fluid,” J. Chem. Phys. 92, 6775–6778 (1990).
K. S. Pitzer, “Second Virial Coefficients for Mixed Gases of Low Polarity,” Fluid Phase Equil. 59, 109–113 (1990).
K. S. Pitzer, “Critical Phenomena in Ionic Fluids,” Acc. Chem. Res. 23, 333–338 (1990).
R. R. Singh and K. S. Pitzer, “Reply to Comment on: ‘Near-critical Coexistence Curve and Critical Exponent of an Ionic Fluid,’” J. Chem. Phys. 93, 8406 (1990).
K. Balasubramanian, P. A. Christiansen, and K. S. Pitzer, “Comment on ‘Relativistic Effects in Bonding and Dipole Moments for the Diatomic Hydrides of the Sixth-Row Heavy Elements,’” Phys. Rev. A 43, 2581–2582 (1991).
A. Anderko and K. S. Pitzer, “Equation of State for Pure Fluids and Mixtures Based on a Truncated Virial Expansion,” AIChE J. 37, 1379–1391 (1991).
R. G. Anstiss and K. S. Pitzer, “Thermodynamics of Very Concentrated Aqueous Electrolytes: LiCl, ZnCl2, and ZnCl2-NaCl at 25°C,” J. Solution Chem. 20, 849–858 (1991).
K. S. Pitzer and R. R. Singh, “Reply to Comment on: ‘Rectilinear Diameters and Extended Corresponding States Theory,’” J. Chem. Phys. 95, 9426–9427 (1991).
K. S. Pitzer, “Ion Interaction Approach: Theory and Data Correlation,” in Activity Coefficients in Electrolyte Solutions, 2nd edn., Chap. 3, K. S. Pitzer, ed. (CRC Press, Boca Raton, Florida, 1991).
R. T. Pabalan and K. S. Pitzer, “Mineral Solubilities in Electrolyte Solutions,” in Activity Coefficients in Electrolyte Solutions, 2nd edn., Chap. 7, K. S. Pitzer, ed. (CRC Press, Boca Raton, Florida, 1991).
S. L. Clegg and K. S. Pitzer, “Thermodynamics of Multicomponent, Miscible, Ionic Solutions: Generalized Equations for Symmetrical Electrolytes,” J. Phys. Chem. 96, 3513–3520 (1992); correction, J. Phys. Chem. 98, 1368 (1994).
I-M. Chou, S. M. Sterner, and K. S. Pitzer, “Phase Relations in the System NaCl-KCl-H2O: IV. Differential Thermal Analysis of the Sylvite Liquidus in the KCl-H2O Binary, the Liquidus in the NaCl-KCl-H2O Ternary, and the Solidus in the NaCl-KCl Binary to 2 kb Pressure, and a Summary of Experimental Data for Thermodynamic-PTX Analysis of Solid-Liquid Equilibria at Elevated P-T Conditions,” Geochim. Cosmochim. Acta 56, 2281–2293 (1992).
S. M. Sterner, I-M. Chou, R. T. Downs, and K. S. Pitzer, “Phase Relations in the System NaCl-KCl-H2O: V. Thermodynamic-PTX Analysis of Solid-Liquid Equilibria at High Temperatures and Pressures,” Geochim. Cosmochim. Acta 56, 2295–2309 (1992).
S. L. Clegg, K. S. Pitzer, and P. Brimblecombe, “Thermodynamics of Multicomponent, Miscible, Ionic Solutions. 2. Mixtures Including Unsymmetrical Electrolytes,” J. Phys. Chem. 96, 9470–9479 (1992); correction, J. Phys. Chem. 98, 1368 (1994).
A. Anderko and K. S. Pitzer, “Equation of State for Pure Sodium Chloride,” Fluid Phase Equil. 79, 103–112 (1992).
K. S. Pitzer, A. Anderko, and S. M. Sterner, “Virial Coefficients and Equations of State for Mixed Fluids; Application to CH4-H2O,” Fluid Phase Equil. 79, 125–137 (1992).
R. N. Roy, K. M. Vogel, C. E. Good, W. B. Davis, L. N. Roy, D. A. Johnson, A. R. Felmy, and K. S. Pitzer, “Activity Coefficients in Electrolyte Mixtures: HCl + ThCl4 + H2O for 5–55°C,” J. Phys. Chem. 96, 11065–11072 (1992).
K. S. Pitzer, “Thermodynamics of Natural and Industrial Waters,” J. Chem. Thermodyn. 25, 7–26 (1993).
J. K. Hovey, K. S. Pitzer, and J. A. Rard, “Thermodynamics of Na2SO4(aq) at Temperatures T from 273 K to 373 K and of {(1−y)H2SO4 + yNa2SO4}(aq) at T = 298.15 K,” J. Chem. Thermodyn. 25, 173–192 (1993).
K. S. Pitzer and Y. Shi, “Thermodynamics of Calcium Chloride in Highly Concentrated Aqueous Solution and in Hydrated Crystals,” J. Solution Chem. 22, 99–105 (1993).
A. Anderko and K. S. Pitzer, “Equation-of-State Representation of Phase Equilibria and Volumetric Properties of the System NaCl-H2O Above 573 K,” Geochim. Cosmochim. Acta 57, 1657–1680 (1993).
A. Anderko, J. P. Chan, and K. S. Pitzer, “On the Apparent Molar Volumes of Nonelectrolytes in Water,” J. Solution Chem. 22, 369–382 (1993).
K. S. Pitzer and S. M. Sterner, “Equations of State for Solid NaCl-KCl and Saturated Liquid NaCl-KCl-H2O,” Thermochim. Acta 218, 413–423 (1993).
A. Anderko and K. S. Pitzer, “Phase Equilibria and Volumetric Properties of the Systems KCl-H2O and NaCl-KCl-H2O Above 573 K: Equation of State Representation,” Geochim. Cosmochim. Acta 57, 4885–4897 (1993).
K. S. Pitzer, “Joel Henry Hildebrand,” in Biographical Memoirs, Vol. 62 (National Academy Press, Washington, D.C., 1993), pp. 225–257.
C. S. Oakes, R. J. Bodnar, J. M. Simonson, and K. S. Pitzer “Critical and Supercritical Properties for 0.3 to 3.0 mol-kg−1 CaCl2(aq),” Geochim. Cosmochim. Acta 58, 2421–2431 (1994).
S. L. Clegg, J. A. Rard, and K. S. Pitzer, “Thermodynamic Properties of 0–6 mol kg−1 Aqueous Sulfuric Acid from 273.15 to 328.15 K,” J. Chem. Soc. Faraday Trans. 90, 1875–1894 (1994).
K. S. Pitzer and C. S. Oakes, “Thermodynamics of Calcium Chloride in Concentrated Aqueous Solutions and in Crystals,” J. Chem. Eng. Data 39, 553–559 (1994).
K. S. Pitzer and S. M. Sterner, “Equations of State Valid Continuously from Zero to Extreme Pressures for H2O and CO2” J. Chem. Phys. 101, 3111–3116 (1994).
T. Narayanan and K. S. Pitzer, “Critical Behavior of Ionic Fluids,” J. Phys. Chem. 98, 9170–9174 (1994).
B. S. Krumgalz, R. Pogorelsky, Ya. A. Iosilevskii, A. Weiser, and K. S. Pitzer, “Ion Interaction Approach for Volumetric Calculations for Solutions of Single Electrolytes at 25°C,” J. Solution Chem. 23, 849–875 (1994).
T. Narayanan and K. S. Pitzer, “Mean-Field to Ising Crossover in Ionic Fluids,” Phys. Rev. Lett. 73, 3002–3005 (1994).
S. M. Sterner and K. S. Pitzer, “An Equation of State for Carbon Dioxide Valid from Zero to Extreme Pressures,” Contrib. Mineral. Petrol. 117, 362–374 (1994).
T. Narayanan and K. S. Pitzer, “Turbidity of a Near Critical Ionic Fluid,” Int. J. Thermophys. 15, 1037–1043 (1994).
S. Jiang and K. S. Pitzer, “Thermodynamic Properties of Mixtures of Dipolar and Quadrupolar Hard Spheres: Theory and Simulation,” J. Chem. Phys. 102, 7632–7640 (1995).
T. Narayanan and K. S. Pitzer, “Critical Phenomena in Ionic Fluids: A Systematic Investigation of the Crossover Behavior,” J. Chem. Phys. 102, 8118–8131 (1995).
C. S. Oakes, R. J. Bodnar, J. M. Simonson, and K. S. Pitzer, “CaCl2-H2O in the Supercritical and Two-Phase Ranges,” Int. J. Thermophys. 16, 483–492 (1995).
K. S. Pitzer and S. M. Sterner, “Equations of State Valid Continuously from Zero to Extreme Pressures with H2O and CO2 as Examples,” Int. J. Thermophys. 16, 511–518 (1995).
K. S. Pitzer, “Ionic Fluids: Near-Critical and Related Properties,” J. Phys. Chem. 99, 13070–13077 (1995).
B. S. Krumgalz, R. Pogorelsky, and K. S. Pitzer, “Ion Interaction Approach to Calculations of Volumetric Properties of Aqueous Multiple-Solute Electrolyte Solutions,” J. Solution Chem. 24, 1025–1038 (1995).
S. Jiang and K. S. Pitzer, “Phase Equilibria and Volumetric Properties of Aqueous CaCl2 by an Equation of State,” AIChE J. 42, 585–594 (1996).
K. S. Pitzer and S. Jiang, “Equation of State for NaCl-H2O: Comparison with Mineral Dehydration Equilibria,” Contrib. Mineral. Petrol. 122, 428–430 (1996).
K. S. Pitzer and D. A. Shirley, “William Francis Giauque,” in Biographical Memoirs, Vol. 69 (National Academy Press, Washington, D. C., 1996), pp. 39–57.
K. S. Pitzer, “Sodium Chloride Vapor at Very High Temperatures: Linear Polymers are Important,” J. Chem. Phys. 104, 6724–6729 (1996).
B. S. Krumgalz, R. Pogorelsky, and K. S. Pitzer, “Volumetric Properties of Single Aqueous Electrolytes from Zero to Saturation Concentration at 298.15 K Represented by Pitzer's Ion-Interaction Equations,” J. Phys. Chem. Ref. Data 25, 663–689 (1996).
Z. Li and K. S. Pitzer, “Thermodynamics of Aqueous KOH over the Full Range to Saturation and to 573 K,” J. Solution Chem. 25, 813–823 (1996).
L. N. Roy, T. M. Beasley, K. M. Kuhler, J. K. Bice, W. S. Good, R. N. Roy, and K. S. Pitzer, “The System HCl + InCl3 + H2O from 5 to 55°C: Application of Harned's Rule,” J. Solution Chem. 25, 1241–1259 (1996).
S. V. Petrenko and K. S. Pitzer, “Thermodynamics of Aqueous NaOH over the Complete Composition Range and to 523 K and 400 MPa,” J. Phys. Chem. B 101, 3589–3595 (1997).
K. S. Pitzer, R. N. Roy, and P. Wang, “Thermodynamics of the System InCl3-HCl-H2O at 25°C,” J. Phys. Chem. B 101, 4120–4126 (1997).
P. Wang, C. S. Oakes, and K. S. Pitzer, “Thermodynamics of Aqueous Mixtures of Magnesium Chloride with Sodium Chloride from 298.15 to 573.15 K. New Measurements of the Enthalpies of Mixing and of Dilution,” J. Chem. Eng. Data 42, 1101–1110 (1997).
K. S. Pitzer and B. Das, “Thermodynamic Properties of Na2SO4(aq) above 200°C,” Geochim. Cosmochim. Acta 62, 915–916 (1998).
C. S. Oakes, K. S. Pitzer, and S. M. Sterner, “The System NaCl-CaCl2-H2O: Part 3. Heats of Dilution and Mixing at 373 to 573 K and 21.5 MPa Using a New High-Temperature, Flow-Through Calorimeter,” Geochim. Cosmochim. Acta 62, 1133–1146 (1998).
K. S. Pitzer, “Aqueous Electrolytes at Near-Critical and Supercritical Temperatures,” Int. J. Thermophys. 19, 355–366 (1998).
K. S. Pitzer, R. N. Roy, and P. Wang, “Thermodynamics of the System InCl3-HCl-H2O at 25°C,” Int. J. Thermophys. 19, 731–738 (1998).
P. Wang, C. S. Oakes, and K. S. Pitzer, “Thermodynamics of the System MgCl2-NaCl-H2O to 573 K: New Measurements of Heat of Mixing and Heat of Dilution,” Int. J. Thermophys. 19, 739–748 (1998).
S. M. Sterner, A. R. Felmy, C. S. Oakes, and K. S. Pitzer, “Correlation of Thermodynamic Data for Aqueous Electrolyte Solutions to Very High Ionic Strengths Using INSIGHT: Vapor Saturated Water Activity in the System CaCl2-H2O to 250°C and Solid Saturation,” Int. J. Thermophys. 19, 761–770 (1998).
P. Wang, K. S. Pitzer, and J. M. Simonson, “Thermodynamic Properties of Aqueous Magnesium Chloride Solutions from 250 to 600 K and to 100 MPa,” J. Phys. Chem. Ref. Data 27, 971–991 (1998).
K. S. Pitzer, P. Wang, J. A. Rard, and S. L. Clegg, “Thermodynamics of Electrolytes. 13. Ionic-Strength Dependence of Higher-Order Terms; Equations for CaCl2 and MgCl2.” J. Solution Chem. 28, 265–282 (1999).
B. Das and K. S. Pitzer, “Thermodynamic Properties of K2SO4(aq) under Superambient Conditions,” J. Solution Chem. 28, 283–290 (1999).
B. S. Krumgalz, R. Pogorelskii, and K. S. Pitzer, “Volumetric Ion Interaction Parameters for Single-Solute Electrolyte Aqueous Solutions at Various Temperatures,” J. Phys. Chem. Ref. Data, submitted.
B. Das and K. S. Pitzer, “Osmotic and Activity Coefficients of KF(aq) Under High Pressures,” Z. Phys. Chem., submitted.
B. Das and K. S. Pitzer, “Thermodynamics of Aqueous Solutions of p-Toluenesulfonic Acid and Some Alkali Metal Salts from 298.15 to 353.15 K,” Bull. Chem. Soc. Jpn., submitted.
Books
F. D. Rossini, K. S. Pitzer, W. J. Taylor, J. E. Kilpatrick, C. W. Beckett, M. D. Williams, and H. C. Werner, Selected Values of Properties of Hydrocarbons, National Bureau of Standards Circular C461 (U. S. Government Printing Office, Washington, D. C., 1947).
F. D. Rossini, K. S. Pitzer, R. L. Arnett, R. M. Brown, and G. C. Pimentel, Selected Values of Physical and Thermodynamic Properties of Hydrocarbons and Related Compounds (published for the American Petroleum Institute by the Carnegie Press, Pittsburgh, PA, 1953). (This is essentially a second edition of the previous book.)
K. S. Pitzer, Quantum Chemistry (Prentice-Hall, Englewood Cliffs, NJ, 1953).
K. S. Pitzer and L. Brewer, 2nd edn. of G. N. Lewis and M. Randall's Thermodynamics (McGraw-Hill, New York, 1961).
K. S. Pitzer, ed., Activity Coefficients in Electrolyte Solutions, 2nd edn. (CRC Press, Boca Raton, 1991).
K. S. Pitzer, Molecular Structure and Statistical Thermodynamics: Selected Papers of Kenneth S. Pitzer (World Scientific, Singapore, 1993) (Comprised of selected papers with added comments.)
K. S. Pitzer, Thermodynamics, 3rd edn. (McGraw-Hill, New York, 1995).
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Memorial Tribute Kenneth Sanborn Pitzer 1914–1997. Journal of Solution Chemistry 28, 247–264 (1999). https://doi.org/10.1023/A:1022619709105
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DOI: https://doi.org/10.1023/A:1022619709105