Skip to main content
SpringerLink
Log in

Study of the 1-chloro-2,4-dinitrobenzene + oh- reaction in tetradecyltrimethylammonium bromide aqueous micellar solutions

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The 1-chloro-2,4-dinitrobenzene + OH- reaction was studied in tetradecyltrimethylammonium bromide aqueous micellar solutions. Influence of changes in [surfactant] as well as in [NaOH] on the observed rate constant were rationalized by using pseudophase kinetic models. At high hydroxide ions concentration an additional pathway across the micellar boundary had to be considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. a) J.H. Fendler, E.J. Fendler: Catalysis in Micellar and Macromolecular Systems.Academic Press, New York 1975; b) J.H. Fendler: Membrane Mimetic Chemistry. Wiley Interscience, New York 1982; c) K. Martinek, A.K. Yatsimirsky, A.V. Levashov, I.V. Berezin: Micellization, Solubilization and Microemulsions.K.L. Mittal ed., Vol. 2, p. 489; Plenum Press, New York 1977; d) S. Tascioglu: Tetrahedron, 52, 11113 (1996); e) L.S. Romsted, C.A. Bunton, J. Yao: Curr. Opin. Colloid Interface Sci.,2, 622 (1997); f) M. Muñoz, A. Rodríguez, M.M. Graciani, M.L. Moyá: Int. J. Chem. Kinet.,34, 445 (2002); g) M.M. Graciani, A. Rodríguez, M. Muñoz, M.L. Moyá: Langmuir,18, 3476 (2002); h) M.M. Graciani, A. Rodríguez, M. Muñoz, M.L. Moyá: React. Kinet. Catal. Lett.,76, 11 (2002).

    Google Scholar 

  2. a) F. Nome, A.F. Rubira, C. Franco, L.G. Ionescu: J. Phys. Chem.,86, 1881 (1982); b) E. Stadler, D. Zannette, M.C. Rezende, F. Nome: J. Phys. Chem.,88, 1982 (1984); c) M. Gonsalves, S. Probst, M.C. Rezende, F. Nome, C. Zucco, D. Zanette: J. Phys. Chem.,89, 1127 (1985); d) M. Muñoz, A. Rodríguez, M.M. Graciani, J.D. Mozo, M.L. Moyá: Langmuir,14, 3524 (1998); e) M. Muñoz, A. Rodríguez, M.M. Graciani, M.L. Moyá: Langmuir,15, 2254 (1999).

    Article  CAS  Google Scholar 

  3. M. Muñoz: Ph.D., University of Seville.

  4. A. Rodríguez, M. Muñoz, M.M. Graciani, M.L. Moyá: J. Colloid Interface Sci.,248, 455 (2002).

    Article  Google Scholar 

  5. T. Imae, S. Ikeda: J. Phys. Chem.,90, 5216 (1986).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento de Química Física, Universidad de Sevilla, C/ Profesor García González s/n, 41012, Sevilla, Spain

    María del Mar Graciani, Amalia Rodríguez, María Muñoz & María Luisa Moyá

Authors
  1. María del Mar Graciani
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Amalia Rodríguez
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. María Muñoz
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. María Luisa Moyá
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to María Luisa Moyá.

Rights and permissions

Reprints and permissions

About this article

Cite this article

del Mar Graciani, M., Rodríguez, A., Muñoz, M. et al. Study of the 1-chloro-2,4-dinitrobenzene + oh- reaction in tetradecyltrimethylammonium bromide aqueous micellar solutions. Reaction Kinetics and Catalysis Letters 78, 113–119 (2003). https://doi.org/10.1023/A:1022570001477

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1022570001477

Search

Navigation