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Substituted iron selenocarboxylate complexes CpFe(CO)(EPh3)SeCOR (E = P, As, Sb)

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Abstract

Photolytic substitutions of iron selenocarboxylate complexes CpFe(CO)2SeCOR with triphenylphosphine, triphenylarsine or triphenylantimony (EPh3) gave exclusively the monosubstituted complexes CpFe(CO)(EPh3)SeCOR [R = 3,5-C6H3(NO2)2 (1), 4-C6H4NO2 (2), Ph (3), 2-C6H4Me (4), and E = P (a), As (b), Sb (c)] in high yields.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Jordan University of Science and Technology, PO Box 3030, Irbid, 22110, Jordan

    Mohammad El-khateeb & Anas Lataifeh

  2. Chemistry Department, Faculty of Science, Yarmouk University, Irbid, Jordan

    Ibrahim Jibril

Authors
  1. Mohammad El-khateeb
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  2. Anas Lataifeh
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  3. Ibrahim Jibril
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El-khateeb, M., Lataifeh, A. & Jibril, I. Substituted iron selenocarboxylate complexes CpFe(CO)(EPh3)SeCOR (E = P, As, Sb). Transition Metal Chemistry 28, 85–87 (2003). https://doi.org/10.1023/A:1022559414990

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