Abstract
The novel (E,E)-dioxime, 5,6:ll,12:17,18-tribenzo-2,3-bis(hydroxyimino)-7,16-dithia-9, 14-dioxo-l,4,10,13-tetraazacyclooctadecane (H2L) has been synthesized by reacting (E,E)-dichloroglyoxime (2) with 2,3:8,9:14,15-tribenzo-4,13-di-thia-6,11-dioxa-l,7,10,16-tetraazahexzadecane (3), prepared by the reaction of N,N′-bis(chloroacetyl)-1, 2-phenylene-diamine (1) with 2-aminothiophenol. Mononuclear complexes (4, 5) of this ligand have been synthesized by reacting the vic-dioxime (H2L) with K2PtCl4 and NiCl2 · 6H2O, respectively. Heterotrinuclear complexes (6)and(7) have been prepared by the reaction of (4) and (5) mononuclear complexes with [Cu(MeCN)4]PF6. The structures of the vic-dioxime and its mono and trinuclear complexes were identified by elemental analysis, 1H- and 13C-n.m.r, i.r. and m.s. data.
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Kantekin, H., Dilber, G., Gök, Y. et al. A new (E,E)-dioxime and its mono and heterotrinuclear complexes containing an 18-membered dithiatetraazamacrocycle. Transition Metal Chemistry 28, 51–57 (2003). https://doi.org/10.1023/A:1022540717560
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DOI: https://doi.org/10.1023/A:1022540717560