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Hydrogen occluded in sulfide catalysts: evidence from the temperature programmed heating technique

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Abstract

Strongly bonded hydrogen is found in alumina supported sulfide Co, Ni, Mo, (Co, Mo) and (Ni, Mo) catalysts. This hydrogen is desorbed from the catalysts in the temperature range of 500-750oC and seems to be occluded in the corresponding sulfide matrix. Possible sites of its localization in the sulfide crystal lattice are discussed.

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REFERENCES

  1. J.L. Falcorner, J.A. Schwarz: Catal. Rev.-Sci. Eng., 25, 141 (1983).

    Google Scholar 

  2. R.J. Cvetanovic, Y. Amenomiya: Catal. Revs.,6, 21 (1972).

    CAS  Google Scholar 

  3. R.C. Hoodless, R.B. Moyes, P.B. Wells: Bull. Soc. Chim. Belg., 93, 673 (1984).

    Article  CAS  Google Scholar 

  4. V.I. Erofeev, I.V. Kaletchits: J. Catal.,86, 55 (1984).

    Article  CAS  Google Scholar 

  5. X.S. Li., Q. Xin, P. Grange, B. Delmon: J. Catal., 137, 385 (1992).

    Article  CAS  Google Scholar 

  6. S. Kasztelan: Langmuir, 6, 590 (1990).

    Article  CAS  Google Scholar 

  7. I.I. Zakharov, A.N. Startsev, G.M. Zhidomirov: J. Mol. Catal., 119,437 (1997).

    Article  CAS  Google Scholar 

  8. I.I. Zakharov, A.N. Startsev, G.M. Zhidomirov, V.N. Parmon: J. Mol. Catal., A: Chemical, 137, 101 (1999).

    Article  CAS  Google Scholar 

  9. A.N. Startsev, A.V. Kalinkin, I.I. Zakharov, D.G. Aksenov, V.N. Parmon: J. Mol. Catal., A: Chemical,151,171 (2000).

    Article  CAS  Google Scholar 

  10. I.I. Zakharov, A.N. Startsev: J. Phys. Chem. B , 104, 9025 (2000).

    Article  CAS  Google Scholar 

  11. A.N. Startsev: J. Mol. Catal. A: Chemical,152, 1 (2000).

    Article  CAS  Google Scholar 

  12. A.N. Startsev, I.I. Zakharov, V. N. Parmon: J. Mol. Catal. A: Chemical, in press.

  13. Yu.M. Serebrennikova, M.A. Fedotov, S.G. Nikitenko, D.I. Kochubey, A. N. Startsev: Kinet. Catal.,in press.

  14. A.N. Startsev: Catal. Rev.-Sci. Eng., 37, 353 (1995).

    CAS  Google Scholar 

  15. A.F. Wells: Structural Inorganic Chemistry.5th Edition. Clarendon Press, Oxford 1986.

    Google Scholar 

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Shalagina, A., Aleshina, G. & Startsev, A. Hydrogen occluded in sulfide catalysts: evidence from the temperature programmed heating technique. Reaction Kinetics and Catalysis Letters 78, 91–98 (2003). https://doi.org/10.1023/A:1022513916498

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  • DOI: https://doi.org/10.1023/A:1022513916498

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