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Synthesis and crystal structure of [Y(NO3)3(OH2)3]·(Me2-16-crown-5)·H2O

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Abstract

The complex [Y(NO3)3(OH2)3]·(Me2-16-crown-5)·H2O has been prepared and its crystal and molecular structure determined using single crystal X-ray diffraction. The colorless crystals belong to the monoclinic space group P21/n with Z = 4. Lattice parameters are a = 10.420(1), b = 17.257(3), c = 14.646(2) Å, β = 96.79(1)°, V = 2615.1(6) Å3. The yttrium(III) ion is nine-coordinate, bonded to three bidentate nitrate groups and three water molecules. The average Y–O(nitrate) and Y–O(water) distances are 2.42(3) and 2.33(1) Å, respectively. The average HO–H···O hydrogen bonded separation is 2.767Å.

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Authors and Affiliations

  1. Department of Chemistry, Zhongshan University, Guangzhou, 510275, China

    Tongbu Lu, Xinyu Peng & Liangnian Ji

  2. Department of Molecular Chemistry, Faculty of Engineering, Osaka University, 2-1 Yamada-oka, Suita, 565, Japan

    Yoshihisa Inoue

  3. Department of Applied Chemistry, Himeji Institute of Technology, 2167 Shosha, Himeji, Hyogo, 671-22, Japan

    Mikio Ouchi

  4. Chengdu Center of Analysis and Measurement, Acdemia Sinica, Chengdu, 610041, China

    Kaibei Yu

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  1. Tongbu Lu
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  2. Xinyu Peng
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  3. Yoshihisa Inoue
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  4. Mikio Ouchi
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  5. Kaibei Yu
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  6. Liangnian Ji
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Lu, T., Peng, X., Inoue, Y. et al. Synthesis and crystal structure of [Y(NO3)3(OH2)3]·(Me2-16-crown-5)·H2O. Journal of Chemical Crystallography 28, 197–201 (1998). https://doi.org/10.1023/A:1022470227008

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  • DOI: https://doi.org/10.1023/A:1022470227008

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