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Temperature Dependence of the Mössbauer Effect on Prussian Blue Nanowires

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Abstract

Highly ordered Prussian blue nanowires with diameter of about 50 nm and length up to 4 μm have been fabricated by an electrodepositing technology with two-step anodizing anodic aluminum oxide films. The Mössbauer spectra taken between 15 and 300 K indicate that the hyperfine parameters decrease as the temperature increases. The temperature dependence of the quadrupole splitting, the isomer shift and the spectra area are discussed. A decrease of Debye temperature for Prussian blue nanowires was found with respect to that of Prussian blue bulk.

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Authors and Affiliations

  1. Key Lab for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou, 730000, P.R. China

    Pingheng Zhou, Desheng Xue, Haiqing Luo & Huigang Shi

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  1. Pingheng Zhou
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  2. Desheng Xue
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  3. Haiqing Luo
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  4. Huigang Shi
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Zhou, P., Xue, D., Luo, H. et al. Temperature Dependence of the Mössbauer Effect on Prussian Blue Nanowires. Hyperfine Interactions 141, 601–606 (2002). https://doi.org/10.1023/A:1022459126443

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