Abstract
We have studied the spectral-luminescent characteristics of ytterbium and neodymium ions in complexes with new polydentate bis-crown-ether and bis-azacyclic ligands both of whose parts are bound by 2,9-substituted 1,10-phenanthroline. The relationship between the intensity, rare-earth ion luminescence lifetime, and the composition of the coordination sphere of the complexes is established. Using the considered compounds as an example, we show the advantage of the joint influence of screening of the central ion from the effect of high-frequency O–H- and C–H vibrations of the solvent molecules and of the “photoantenna” effect in improvement of the luminescent characteristics of lanthanides.
Similar content being viewed by others
REFERENCES
D. Parker, Coord. Chem. Rev., 205, 109–130 (2000).
V. Alexander, Chem. Rev., 95, 273–342 (1995).
S. Faulkner, A. Beeby, M.-C. Carrie, et al., Inorg. Chem. Commun., 4, 187–190 (2001).
N. Sabbatini, M. Guardigli, and J.-M. Lehn, Coord. Chem. Rev., 123, 201–228 (1993).
J. W. Hofstraat, M. P. Oude Wolbers, F. C. J. M. van Veggel, et al., J. Fluoresc., 8, 301–307 (1998).
Yu. Korovin and N. Rusakova, Rev. Inorg. Chem., 21, 299–329 (2001).
Y. Himeda, K. Hiratani, K. Kasuga, et al., Chem. Lett., No. 12, 1475–1478 (1993).
S. Aime, M. Botta, L. Frullano, et al., Chem. Eur. J., 5, 1253–1260 (1999).
R. B. King and P. R. Heckley, J. Am. Chem. Soc., 96, 3118–3123 (1974).
V. E. Pyatosin, M. P. Tsvirko, K. N. Solov’ev, and T. F. Kachura, Opt. Spektrosk., 52, 269–275 (1982).
A. M. Arif, J. D. Backer-Dirks, C. J. Gray, et al., J. Chem. Soc., Dalton Trans., 1665–1673 (1987).
Guide for Users. HYPERCHEM. Release 5.1, Hypercube, Inc. (1999).
Yu. V. Korovin, Yu. A. Popkov, N. A. Nazarenko, et al., Dokl. Akad. Nauk UkSSR, No. 8, 150–153 (1991).
L. Di Bari, G. Pintacuda, P. Salvadori, et al., J. Am. Chem. Soc., 122, 9257–9264 (2000).
F. Pina, M. A. Bernardo, and E. Garcia-Espanña, Eur. J. Inorg. Chem., 2143–2157 (2000).
A. Beeby and S. Faulkner, Chem. Phys. Lett., 266, 116–122 (1997).
M. P. Tsvirko, S. B. Meshkova, V. Ya. Venchikov, and D. B. Bol’shoi, Opt. Spektrosk., 87, 950–955 (1999).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Korovin, Y.V., Rusakova, N.V., Popkov, Y.A. et al. Luminescence of Ytterbium and Neodymium in Complexes with Bis-Macrocyclic Ligands. Journal of Applied Spectroscopy 69, 841–844 (2002). https://doi.org/10.1023/A:1022454202549
Issue Date:
DOI: https://doi.org/10.1023/A:1022454202549