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A Procedure for Isolating Desmotropic Forms of Tautomeric Compounds, with 5-Benzylidene-2-mercapto-Δ2-thiazolin-4-one as Example

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Abstract

Reaction of aniline with a mixture of tautomes of 3-benzylidene-4-oxothiazolidine-2-thione, followed by treatment with hydrogen chloride, allowed isolation of the pure desmotropic form of this compound, 5-benzylidene-2-mercapto-Δ2-thiazolin-4-one.

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REFERENCES

  1. Henichart, J.P., Houssin, R., Lablanche, B., et al., J. Heterocyclic Chem., 1977, vol. 14, no. 3, pp. 439-442.

    Google Scholar 

  2. Kabachnik, M.I., Zh. Vses. Khim. O-va im. D.I. Mendeleeva, 1962, vol. 7, no. 3, pp. 263-273.

    Google Scholar 

  3. Kitaigorodskii, A.I., Molekulyarnye kristally (Molecular Crystals), Moscow: Nauka, 1971.

    Google Scholar 

  4. Uner, M., Kovac, S., Martvon, A., and Jezek, M., Chem. Zvesti, 1978, vol. 32, no. 4, pp. 486-492.

    Google Scholar 

  5. Kamat, P.V., Laxmeshwar, N.B., and Datar, M.G., J. Indian Chem. Soc., 1971, vol. 48, no. 2, pp. 199-203.

    Google Scholar 

  6. Boer, F.P., Turley, J.W., and Remoortere, F.P., J. Chem. Soc., Chem. Commun., 1972, no. 9, pp. 573-574.

  7. Rapi, G., Ginanneschi, M., and Belgodere, E., J. Heterocyclic Chem., 1972, vol. 9, no. 2, pp. 285-292.

    Google Scholar 

  8. Ginak, A.I., V'yunov, K.A., and Sochilin, E.G., Zh. Org. Khim., 1971, vol. 7, no. 7, pp. 1500-1506.

    Google Scholar 

  9. Ginak, A.I., V'yunov, K.A., and Ramsh, S.M., Zh. Org. Khim., 1983, vol. 19, no. 1, pp. 212-215.

    Google Scholar 

  10. Sushchev, V.G., Ramsh, S.M., Ginak, A.I., and Sochilin, E.G., Zh. Org. Khim., 1979, vol. 15, no. 8, pp. 1720-1723.

    Google Scholar 

  11. Ginak, A.I., V'yunov, K.A., and Sochilin, E.G., Khim. Geterotsikl. Soedin., 1971, no. 3, pp. 858-859.

  12. Lebedev, R.S., Zh. Prikl. Spektrosk., 1971, vol. 15, no. 1, pp. 148-150.

    Google Scholar 

  13. V'yunov, K.A., Ginak, A.I., and Sochilin, E.G., Zh. Prikl. Spektrosk., 1977, vol. 27, no. 6, pp. 1071-1077.

    Google Scholar 

  14. Ginak, A.I., V'yunov, K.A., and Sochilin, E.G., Zh. Prikl. Khim., 1971, vol. 44, no. 9, pp. 2123-2126.

    Google Scholar 

  15. Brown, F.C., Chem. Rev., 1961, vol. 61, no. 5, pp. 463-521.

    Google Scholar 

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Aronova, E.B., Ginak, A.I. A Procedure for Isolating Desmotropic Forms of Tautomeric Compounds, with 5-Benzylidene-2-mercapto-Δ2-thiazolin-4-one as Example. Russian Journal of Applied Chemistry 75, 1885–1886 (2002). https://doi.org/10.1023/A:1022299228532

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