Skip to main content
SpringerLink
Log in

Polymerization of Styrene in the Presence of Nitroxyl Radicals Generated Directly in the Course of the Polymer Synthesis (in situ)

  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The features of radical polymerization of styrene in the presence of nitroxyl radicals generated directly in the course of the polymer synthesis (in situ) by irreversible reaction of stable organic compounds 2-methyl-2-nitrosopropane, C-phenyl-N-tert-butylnitrone, and nitrosodurene with propagating polymer radicals were studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Georges, M.K., Veregin, R.P.N., Kazmaier, P.M., and Hamer, G.K., Polym. Mater. Sci. Eng., 1993, vol. 68, pp. 6-9.

    Google Scholar 

  2. Smirnov, B.R., Vysokomol. Soedin., Ser. A, 1990, vol. 32, no. 3, pp. 583-589.

    Google Scholar 

  3. Otsu, T. and Matsumoto, A., Adv. Polym. Sci., 1998, vol. 136, pp. 75-137.

    Google Scholar 

  4. Matyjaszewski, K., Controlled/Living Radical Polymerization, Oxford: Oxford Univ. Press, 2000.

    Google Scholar 

  5. Korolev, G.V. and Marchenko, A.P., Usp. Khim., 2000, vol. 69, no. 5, pp. 447-475.

    Google Scholar 

  6. Grishin, D.F. and Semenycheva, L.L., Usp. Khim., 2001, vol. 70, no. 5, pp. 486-510.

    Google Scholar 

  7. Zaremskii, M.Yu. and Golubev, V.B., Vysokomol. Soedin., 2001, vol. 43, no. 9, pp. 1689-1728.

    Google Scholar 

  8. Georges, M.K., Veregin, R.P., Kazmaier, P.M., et al., Macromolecules, 1994, vol. 27, no. 24, pp. 7228-7234.

    Google Scholar 

  9. Veregin, R.P.N., Odell, P.G., Michalak, L.M., and Georges, M.K., Macromolecules, 1996, vol. 29, no. 11, pp. 4161-4168.

    Google Scholar 

  10. Baldovi, M.V., Mohtad, N., and Scaiano, J.C., Macromolecules, 1996, vol. 29, no. 16, pp. 5497-5499.

    Google Scholar 

  11. Odell, P.G., Veregin, R.P.N., Michalak, L.M., and Georges, M.K., Macromolecules, 1997, vol. 30, no. 8, pp. 2232-2235.

    Google Scholar 

  12. Goto, M. and Fukuda, T., Macromolecules, 1997, vol. 30, no. 15, pp. 4272-4276.

    Google Scholar 

  13. Greszta, D. and Matyjaszewski, K., J. Polym. Sci., Polym. Chem. Ed., 1997, vol. 35, no. 9, pp. 1857-1861.

    Google Scholar 

  14. Bon, S.A.F., Chambard, G., and German, A.L., Macromolecules, 1999, vol. 32, no. 25, pp. 8269-8271.

    Google Scholar 

  15. Veregin, R.P.N., Odell, P.G., Michalak, L.M., and Georges, M.K., Macromolecules, 1996, vol. 29, no. 8, pp. 2746-2754.

    Google Scholar 

  16. Miura, Y., Nakamura, N., and Taniguchi, I., Macromolecules, 2001, vol. 34, no. 3, pp. 447-455.

    Google Scholar 

  17. Han, C.H., Drache, M., Baethge, H., and Schmidt-Naace, G., Macromol. Chem. Phys., 1999, vol. 200, no. 7, pp. 1779-1781.

    Google Scholar 

  18. Grishin, D.F., Semionicheva, L.L., and Koliakina, E.V., Mendeleev Commun., 1999, no. 6, pp. 45-47.

  19. Grishin, D.F., Semenycheva, L.L., and Kolyakina, E.V., Vysokomol. Soedin., Ser. A, 1999, vol. 40, no. 4, pp. 609-614.

    Google Scholar 

  20. Kolyakina, E.V., Grishin, D.F., and Semenycheva, L.L., Vysokomol. Soedin., Ser. A, 2001, vol. 43, no. 12, pp. 2092-2196.

    Google Scholar 

  21. Grishin, D.F., Semenycheva, L.L., and Kolyakina, E.V., Zh. Prikl. Khim., 2001, vol. 74, no. 3, pp. 483-486.

    Google Scholar 

  22. Grishin, D.F., Moykin, A.A., Smirnova, E.P., et al., Mendeleev Commun., 2000, no. 5, pp. 152-154.

  23. Grishin, D.F., Pavlovskaya, M.V., and Semenycheva, L.L., Vysokomol. Soedin., Ser. A, 2001, vol. 43, no. 11, pp. 1913-1917.

    Google Scholar 

  24. Grishin, D.F., Pavlovskaya, M.V., and Semenycheva, L.L., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, vol. 44, no. 5, pp. 33-39.

    Google Scholar 

  25. Terabe, S. and Konaka, S., J. Chem. Soc., Perkin Trans. 2, 1972, no. 14, pp. 2163-2172.

    Google Scholar 

  26. Emmons, W.D., J. Am. Chem. Soc., 1957, vol. 79, no. 5, pp. 5739-5744.

    Google Scholar 

  27. Dugar, S.M. and Sogani, N.C., J. Indian Chem. Soc., 1966, vol. 43, no. 4, pp. 289-290.

    Google Scholar 

  28. Organic Syntheses, Blatt, A.H., Ed., New York: Wiley, 1946, 2nd ed., coll. vol. 2.

    Google Scholar 

  29. Praktikum po khimii i fizike polimerov (Practical Course of Polymer Chemistry and Physics), Moscow: Khimiya, 1990.

  30. Entsiklopediya polimerov (Polymer Encyclopedia), Moscow: Sovetskaya Entsiklopediya, 1972, vol. 1.

  31. Rafikov, S.R., Pavlov, S.A., and Tverdokhledova, I.I., Metody opredeleniya molekulyarnykh vesov i polidispersnosti vysokomolekulyarnykh soedinenii (Methods for Determining the Molecular Weights and Polydispersity of Macromolecular Compounds), Moscow: Khimiya, 1963.

    Google Scholar 

  32. Belen'kii, B.G. and Vilenchik, L.Z., Khromatografiya polimerov (Chromatography of Polymers), Moscow: Khimiya, 1978.

    Google Scholar 

  33. Mercier, C. le, Lutz, J.-F., and Margue, S., in Controlled/Living Radical Polymerization, Washington, DC: Am. Chem. Soc., 2000, ch. 8, pp. 109-22.

    Google Scholar 

  34. Zubarev, V.E., Metod spinovykh lovushek (Method of Spin Traps), Moscow: Mosk. Gos. Univ., 1984.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Research Institute of Chemistry, Nizhni Novgorod State University, Nizhni Novgorod, Russia

    M. V. Pavlovskaya, E. V. Kolyakina, V. V. Polyanskova, L. L. Semenycheva & D. F. Grishin

Authors
  1. M. V. Pavlovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Kolyakina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Polyanskova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. L. Semenycheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. F. Grishin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pavlovskaya, M.V., Kolyakina, E.V., Polyanskova, V.V. et al. Polymerization of Styrene in the Presence of Nitroxyl Radicals Generated Directly in the Course of the Polymer Synthesis (in situ). Russian Journal of Applied Chemistry 75, 1868–1872 (2002). https://doi.org/10.1023/A:1022290926714

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1022290926714

Keywords

Search

Navigation