Abstract
The methods of the Kerr effect and solution hydrodynamics were applied to study the electrooptical and hydrodynamic properties of samples of disubstituted polyacetylenes, poly(1-trimethylsilyl-1-propynes), prepared by polymerization of 1-trimethylsilyl-1-propyne with NbCl5 and TaCl5/BuLi as catalysts. The experimental electrooptical characteristics of polymers were compared with those calculated by PM3 semiempirical quantum-chemical method.
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Evlampieva, N.P., Yakimanskii, A.V., Pavlov, G.M. et al. Electrooptical and Conformational Properties of Poly(1-Trimethylsilyl-1-Propynes) with Different Chain Microstructures. Russian Journal of Applied Chemistry 75, 1665–1672 (2002). https://doi.org/10.1023/A:1022240120837
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DOI: https://doi.org/10.1023/A:1022240120837