Abstract
The kinetic and thermodynamic parameters of amination of PCA—PGMA graft copolymer with p-phenylenediamine (initial reaction rate, reaction order in chemically active groups, and effective activation energy were determined. The high efficacy of p-phenylenediamine in splitting of PGMA α-oxide groups, almost at the level of diamines of aliphatic structure, was demonstrated.
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Druzhinina, T.V., Kardash, K.V. & Aldoshina, E.M. Polymer-Analog Transformations of Polycaproamide—Polyglycidyl Dimethacrylate Graft Copolymers under the Effect of Aromatic Diamine. Fibre Chemistry 34, 324–328 (2002). https://doi.org/10.1023/A:1022198732474
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DOI: https://doi.org/10.1023/A:1022198732474