Abstract
Five-coordinate organometallic complexes RIn(TAPPh8) (R = Ph, Bu) were synthesized by the reactions of chloro(octaphenyltetraazaporphyrinato)indium(iii) ClIn(TAPPh8) with organolithium and organomagnesium compounds. The optical, IR, and 1H NMR spectra of the complexes were studied. In the presence of pyridine, the photochemical insertion of CO2 occurs at the In—C bond to form the carboxylate complexes (RCOO)In(TAPPh8). A study of the kinetics of this reaction showed a higher stability of the In—C bond in the aryl PhIn(TAPPh8) complex than that in the alkyl complex BuIn(TAPPh8). The mechanism of the reaction was proposed.
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References
M. Hanack and H. Heckman, Eur. J. Inorg. Chem., 1998, 1, 367.
P. A. Stuzhin, O. V. Mal´chugina, S. Wolowiec, L. Latos Grazynzki, and B. D. Berezin, Mendeleev Commun., 1998, 143.
P. Cocolios, R. Guilard, and P. Fournari, J. Organomet. Chem., 1979, 179, 311.
S. S. Dvonikov, V. N. Knyukshto, V. A. Kuzmitsky, A. Shulga, and K. N. Solovyov, J. Luminescence, 1981, 23, 373.
P. A. Stuzhin, I. S. Migalova, and Kh. Khomborg, Koord. Khim., 2000, 26, 9 [Russ. J. Coord. Chem., 2000, 26 (Engl. Transl.)].
P. A. Stuzhin, M. Hamdush, and U. Ziener, Inorg. Chim. Acta, 1995, 236, 131.
K. N. Colov´ev, L. L. Gladkov, A. S. Starukhin, and S. F. Shkirman, Spektroskopiya porfirinov: kolebatel´nye sostoyaniya [Spectroscopy of Porphyrins: Vibrational States], Nauka i Tekhnika, Minsk, 1985, 416 pp. (in Russian).
L. J. Bellami, The Infrared Spectra of Complex Molecules, Chapman and Hall, London, 1975, 393 pp.
P. A. Stuzhin and O. G. Khelevina, Coord. Chem. Rev., 1996, 147, 41.
O. G. Khelevina, P. A. Stuzhin, I. S. Migalova, and O. V. Shukhto, Zh. Obshch. Khim., 2001, 71, 1738 [Russ. J. Gen. Chem., 2001, 71 (Engl. Transl.)].
K. M. Kadish, B. Boisselier-Cocolios, P. Cocolios, and R. Guilard, Inorg. Chem., 1985, 24, 2139.
P. Cocolios, R. Guilard, D. Bayeul, and C. Lecomte, Inorg. Chem., 1985, 24, 2058.
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley and Sons, New York, 1978.
S. V. Zaitseva, S. A. Zdanovich, and T. A. Ageeva, Molecules, 2001, 5, 1495.
J. C. Dobrowolski and M. H. Jamroz, J. Mol. Struct., 1992, 275, 211.
B. Aβmann, G. Ostendorp, and H. Homborg, Z. Anorg. Allg. Chem., 1995, 621, 1708.
K. Schweiger, A. Kienast, B. Latte, and H. Homborg, Z. Anorg. Allg. Chem., 1997, 623, 973.
B. Aβmann, A. Franken, and H. Homborg, Z. Naturforsch., 1996, 51b, 325.
H. Brand and J. Arnold, Coord. Chem. Rev., 1995, 140, 137.
R. D. Shannon and C. T. Prewitt, Acta Crystallogr., 1969, B25, 925.
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Mal"chugina, O.V., Stuzhin, P.A. Synthesis and study of organometallic complexes of octaphenyltetraazaporphyrinatoindium(iii). Russian Chemical Bulletin 51, 2261–2267 (2002). https://doi.org/10.1023/A:1022143604268
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DOI: https://doi.org/10.1023/A:1022143604268