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Crystal structure and thermal stability of Ni151.5Pb24S92. Search for selenium- and tellurium-containing analogs

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Abstract

The crystal structure of the subvalent nickel—lead sulfide, which has been described previously as Ni60Pb9S31, was established and the composition of this sulfide was refined based on powder X-ray diffraction data. The true Ni151.5Pb24S92 composition of this compound was confirmed by the EDX techniques. The temperature range of stability of this compound (490—578 °C) was refined by differential thermal analysis. In the search for analogs, the triangulation of the Ni—Pb—Se and Ni—Pb—Te systems at 540 °C was carried out for the first time. No new ternary phases were detected.

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Authors and Affiliations

  1. Department of Materials Science, M. V. Lomonosov Moscow State University, Leninskie Gory, 119992, Moscow, Russian Federation

    A. I. Baranov & A. A. Isaeva

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119992, Moscow, Russian Federation

    B. A. Popovkin & R. V. Shpanchenko

Authors
  1. A. I. Baranov
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  2. A. A. Isaeva
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  3. B. A. Popovkin
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  4. R. V. Shpanchenko
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Baranov, A.I., Isaeva, A.A., Popovkin, B.A. et al. Crystal structure and thermal stability of Ni151.5Pb24S92. Search for selenium- and tellurium-containing analogs. Russian Chemical Bulletin 51, 2139–2144 (2002). https://doi.org/10.1023/A:1022142412020

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