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The Vinylation of Aryl Iodides Catalyzed by Silica-Supported Poly-γ-aminopropylsilica Ni, Cu and Co Complexes

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Abstract

Silica-supported poly-γ-aminopropylsilica Ni, Cu and Co complexes were prepared from poly-γ-aminopropylsilane and fumed silica, followed by treatment with metal acetate in ethanol. These catalysts are highly active and stereoselective for vinylation of aryl iodides with olefins. They give a variety of trans-substituted products in high yields in both polar and non-polar solvents at 120-150 °C, and can be reused without loss in activity.

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Authors and Affiliations

  1. Institute of Catalysis, Zhejiang University, Hangzhou, 310028, P.R. China

    Yuanfa Yang, Renxian Zhou, Shaofen Zhao & Xiaoming Zheng

  2. Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, 321004, P.R. China

    Yuanfa Yang

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  1. Yuanfa Yang
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  2. Renxian Zhou
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  3. Shaofen Zhao
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  4. Xiaoming Zheng
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Yang, Y., Zhou, R., Zhao, S. et al. The Vinylation of Aryl Iodides Catalyzed by Silica-Supported Poly-γ-aminopropylsilica Ni, Cu and Co Complexes. Catalysis Letters 85, 87–90 (2003). https://doi.org/10.1023/A:1022124925590

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  • DOI: https://doi.org/10.1023/A:1022124925590

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