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Gas Hydrate Frameworks of Allen's Polyhedra. 1. Frameworks on 3–5 Nets

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Abstract

The structures of water molecule frameworks built up of 512, 51262, 51263, and 51264 polyhedra are discussed. In the frameworks of such polyhedra, it is possible to distinguish layers; the centers of the polyhedra belonging to a layer are at the nodes of a planar network consisting of triangular, pentagonal, and hexagonal meshes. The structure of one layer entirely determines the structure of the whole framework. An analysis is given of the structure and topology of frameworks whose layers are constructed on pentagon‐trigonal nets. It is shown that these frameworks can be constructed from two types of polyhedral blocks closely packed in space.

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  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    V. I. Kosyakov

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Kosyakov, V.I. Gas Hydrate Frameworks of Allen's Polyhedra. 1. Frameworks on 3–5 Nets. Journal of Structural Chemistry 43, 622–631 (2002). https://doi.org/10.1023/A:1022048503998

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