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Reactions of Triruthenium Clusters with Quinolines: X-Ray Structures of [Ru3(μ-CO)(CO)7{μ3-η2-P(C6H5)CH2P(C6H5)2)}{μ-η2-C9H5(CH3)N}] and [Ru3(CO)10(μ-H){μ-η2-C9H6N}]

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Abstract

The reactions of [Ru3(CO)10(μ-dppm)] 4 with quinolines afforded [Ru3 (μ-CO)(CO)7{μ3-η2-P(C6H5)CH2P(C6H5)2)}{μ-η2-C9H5(R)N}] (8, R = 4-Me; 9, R = H) as the major products along with small amounts of known compound [Ru3(CO)9{μ3-η3-P(C6H5)CH2P(C6H5)(C6H4)}] 5. The molecular structure of 8 has been determined by single crystal X-ray studies. The reaction of 5 with 4-methylquinoline in refluxing cyclohexane afforded 8 and two known dinuclear compounds, [Ru2(CO)6{μ-CH2P(C6H5)(C6H4)P(C6H5}] 10 and [Ru2(CO)6 {μ-(C6H4)P(C6H5)(CH2)P(C6H5}] 11, in 40, 12, and 10% yields, respectively. The compounds 10 and 11 are also formed from the thermolysis of 4 in addition to the major compound 5. The solid state structure of the previously reported [Ru3(CO)10(η-H){μ-η2-C9H6N}] 2a is also reported for comparison.

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Authors and Affiliations

  1. Department of Chemistry, Jahangirnagar University, Savar, Dhaka, 1342, Bangladesh

    Shariff E. Kabir & Tasneem A. Siddiquee

  2. Department of Chemistry, The University of Montana, Missoula, MT, 59812

    Edward Rosenberg & Ryan Smith

  3. Department of Chemistry, University of Wales Cardiff, P.O. Box 912, Cardiff, CF1 3TB, United Kingdom

    Michael B. Hursthouse & K. M. Abdul Malik

  4. Department of Chemistry, California State University, Northridge, CA, 91330

    Kenneth I. Hardcastle & Mandana Visi

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  1. Shariff E. Kabir
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Kabir, S.E., Siddiquee, T.A., Rosenberg, E. et al. Reactions of Triruthenium Clusters with Quinolines: X-Ray Structures of [Ru3(μ-CO)(CO)7{μ3-η2-P(C6H5)CH2P(C6H5)2)}{μ-η2-C9H5(CH3)N}] and [Ru3(CO)10(μ-H){μ-η2-C9H6N}]. Journal of Cluster Science 9, 185–199 (1998). https://doi.org/10.1023/A:1021994116953

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