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Thermodynamics of Organic Mixtures Containing Amines. II. Excess Molar Volumes at 25°C for Methylbutylamine + Alkane Systems and Eras Characterization of Linear Secondary Amine + Alkane Mixtures

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Abstract

Excess molar volumes, at 25°C and atmospheric pressure for methylbutyl amine + n-hexane; + cyclohexane; + n-octane; n-decane; + n-dodecane; + n-tetradecane, or + n-hexadecane systems are reported from densities measured with a vibrating-tube densimeter. The excess functions, molar enthalpy, and volume, for linear secondary amine + n-alkane systems are discussed in terms of interactional and structural effects. In addition, these solutions, which include amines from dimethyl to dioctylamine, are studied in the framework of the ERAS model. The corresponding ERAS parameters are reported. The agreement between experimental data and ERAS results is good for excess enthalpies, excess Gibbs energies, and excess molar volumes. The larger discrepancies are found for the excess volumes when strong free-volume effects are present in the investigated mixtures. The variation with temperature of the thermodynamic properties is well described by ERAS.

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  1. G.E.T.E.F. Departamento de Termodinámica y Fisica Aplicada, Facultad de Ciencias Universidad de Valladolid, E-47005, Valladolid, Spain

    S. Villa, J. A. González, I. García De La Fuente, N. Riesco & J.C. Cobos

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  1. S. Villa
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  2. J. A. González
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  3. I. García De La Fuente
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Villa, S., González, J.A., De La Fuente, I.G. et al. Thermodynamics of Organic Mixtures Containing Amines. II. Excess Molar Volumes at 25°C for Methylbutylamine + Alkane Systems and Eras Characterization of Linear Secondary Amine + Alkane Mixtures. Journal of Solution Chemistry 31, 1019–1038 (2002). https://doi.org/10.1023/A:1021881627444

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