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Structure and spectroscopic properties of borane-1-trimethylsilylpiperidine

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Abstract

As a new borane source for hydroboration, borane-1-trimethylsilylpiperidine (1) was synthesized from the reaction of diborane with 1-trimethylsilylpiperidine. The molecular structure of 1 was unambiguously determined by a combination of 1H, 13C, and 11B NMR spectra and X-ray single crystal analysis. X-ray crystallographic data for 1: Orthorhombic Pnma (#62), a = 6.4476(6) Å, b = 10.503(1) Å, c = 6.058(2) Å, V = 1087.4(2) Å3, Z = 4.

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Authors and Affiliations

  1. Department of Chemistry, University of Puerto Rico, San Juan, Puerto Rico, 00931

    Jesus R. Medina, Ramon Huertas, John A. Soderquist & Songping D. Huang

Authors
  1. Jesus R. Medina
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  2. Ramon Huertas
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  3. John A. Soderquist
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  4. Songping D. Huang
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Medina, J.R., Huertas, R., Soderquist, J.A. et al. Structure and spectroscopic properties of borane-1-trimethylsilylpiperidine. Journal of Chemical Crystallography 28, 309–311 (1998). https://doi.org/10.1023/A:1021809504986

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  • DOI: https://doi.org/10.1023/A:1021809504986

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