Abstract
The solid-state synthesis of [LiAl2(OH)6]Cl · mH2O at room and elevated temperatures from powdered solid reagents, lithium chloride and gibbsite, is described. The synthesis is performed with the help of different devices including a laboratory mixer, large-scale laboratory arm mixer, and planetary centrifugal mill. The interaction of the components depends on both the dispersity of Al(OH)3 and the nature of lithium chloride. At the initial stage, the interaction is limited by the rate of lithium chloride diffusion through the layer of the product formed. Activation energy, calculated according to the Valency–Carter equation, is 53 ± 5 kJ/mol.
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Menzheres, L.T., Kotsupalo, N.P. & Mamylova, E.V. Solid-State Interaction of Aluminium Hydroxide with Lithium Salts. Journal of Materials Synthesis and Processing 7, 239–244 (1999). https://doi.org/10.1023/A:1021801610573
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DOI: https://doi.org/10.1023/A:1021801610573