Abstract
Freezing point lowerings of aqueous solutions of uranyl sulfate in the concentration range m ≤ 0.40 mol-kg−1 and the activity and osmotic coefficients, which were calculated using the Pitzer equations for 2:2 electrolytes, are presented. Crystallization temperatures are reported for 0 to 13 molar nitric acid and 10–150 g uranium per liter uranyl nitrate–nitric acid–water solutions.
Similar content being viewed by others
REFERENCES
F. R. Bruce, J. M. Fletcher, and H. H. Hyman, eds., Progress in Nuclear Energy, Process Chemistry, Series III, Vol. 2 (Pergamon Press, London, 1958).
A. Vasiliev, J. Russ. Phys-Chem. Soc. 42, 423, 562, 570 (1910).
O. Guempel, Bull. Soc. Chem. Belg. 88, 443 (1929).
R. G. Hart and G. O. Morris, in Progress in Nuclear Energy, Process Chemistry, Series III, Vol. 2, F. R. Bruce, J. M. Fletcher, and H. H. Hyman, eds. (Pergamon Press, London, 1958), pp. 544-545.
C. M. Slansky, in Progress in Nuclear Energy, Process Chemistry, Series III, Vol. 2, F. R. Bruce, J. M. Fletcher, and H. H. Hyman, eds. (Pergamon Press, London, 1958), pp. 535-543.
A. Apelblat, J. Inorg. Nucl. Chem. 39, 1852 (1977).
A. Colani, Bull. Soc. Chim. (Fr.) 39, 1243 (1926).
J. Gaunt, L. J. Bastien, and M. Adelman, Can. J. Chem. 41, 527 (1963).
M. A. Yakimov and V. Ya. Mishin, Radiokhimiya 6, 454 (1964).
M. A. Yakimov, V. Ya. Mishin, and V. K. Philipov, Radiokhimiya 6, 548 (1964).
M. A. Yakimov, V. Ya. Mishin N. F. Nosova, and V. K. Philipov, Radiokhimiya 6, 553 (1964).
R. D. Thibodeau and M. Adelman, Can. J. Chem. 41, 531 (1963).
A. Dittrick, Z. Physik. Chem. 29, 449 (1899).
C. H. Secoy, J. Am. Chem. Soc. 70, 3450 (1948).
R. H. Robinson, J. Chem. Soc., p. 4543 (1952).
R. H. Robinson and R. H. Stokes, Electrolyte Solutions, 2nd rev edn. (Butterworths, London, 1965), p. 502.
K. S. Pitzer, in Activity Coefficients in Electrolyte Solutions, Vol. 1, R. M. Pytkowicz, ed. (CRC Press, Boca Raton, FL, 1979), pp. 157-208.
A. Apelblat, D. Azoulay, and A. Sahar, J. Chem. Soc. Faraday I 69, 1618 (1973).
E. L. Skan and Y. C. Arthur Jr., in Physical Methods in Organic Chemistry, Part I, A. Weissberger, ed. [Wiley (Interscience). New York, 1959], pp. 287-354.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Apelblat, A. Cryoscopic Studies of the Uranyl Sulfate–Water, Uranyl Nitrate–Water, and Uranyl Nitrate–Nitric Acid–Water Systems. Journal of Solution Chemistry 28, 769–776 (1999). https://doi.org/10.1023/A:1021776213704
Issue Date:
DOI: https://doi.org/10.1023/A:1021776213704