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Synthesis, Structure, and Alkylation of N-Methylmorpholinium 5-[2-Cyanoethyl-1-(4-hydroxy-3-methoxyphenyl)-2-thiocarbamoyl]-2,2-dimethyl-6-oxo-1,3-dioxa-4-cyclohexen-4-olate

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Abstract

N-Methylmorpholinium 5-[2-cyanoethyl-1-(4-hydroxy-3-methoxyphenyl)-2-thiocarbamoyl]-2,2-dimethyl-6-oxo-1,3-dioxa-4-cyclohexen-4-olate was obtained from the reaction of 4-hydroxy-3-methoxybenzaldehyde with cyanothioacetamide and Meldrum's acid in the presence of N-methylmorpholine. The molecular and crystal structure of the title compound have been established and its alkylation has been studied.

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Authors and Affiliations

  1. Eastern Ukraine State University, Lugansk, 91034, Ukraine

    S. G. Krivokolysko

  2. Institute of Organic Chemistry, Ukraine National Academy of Sciences, Kiev, 02094, Ukraine

    A. N. Chernega

  3. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 117913, Russia

    V. P. Litvinov

Authors
  1. S. G. Krivokolysko
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  2. A. N. Chernega
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  3. V. P. Litvinov
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Krivokolysko, S.G., Chernega, A.N. & Litvinov, V.P. Synthesis, Structure, and Alkylation of N-Methylmorpholinium 5-[2-Cyanoethyl-1-(4-hydroxy-3-methoxyphenyl)-2-thiocarbamoyl]-2,2-dimethyl-6-oxo-1,3-dioxa-4-cyclohexen-4-olate. Chemistry of Heterocyclic Compounds 38, 1269–1275 (2002). https://doi.org/10.1023/A:1021745916815

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