Skip to main content
SpringerLink
Log in

Synthesis and Study of Potassium Hexabromoiridate(IV)

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

A new method of synthesis of potassium hexabromoiridate(IV) was developed. This complex was studied using X-ray diffraction and elemental analyses and electronic absoprtion, IR, and Raman spectroscopy methods. Crystallographic parameters: a = 10.298(5) Å, V = 1092.1 Å3, Z = 4, space group Fm3m, ρ(calcd) = 4.560 g/cm3; K2[PtCl6] structural type. The thermal decomposition of this salt in an inert atmosphere was investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Giffith, W.P., The Chemistry of the Rarer Platinum Metals (Os, Ru, Ir and Rh), London: Interscience, 1967, p. 233.

    Google Scholar 

  2. Bottger, G.L. and Salvin, A.E., Spectrochim. Acta A, 1972, vol. 28, p. 925.

    Google Scholar 

  3. Jorgensen, C.K., Acta Chem. Scand., 1956, vol. 10, p. 500.

    Google Scholar 

  4. Fergusson, J.E. and Rankin, D.A., Aust. J. Chem., 1983, vol. 36, no. 5, p. 863.

    Google Scholar 

  5. Kelly, D.A. and Good, M.L., Spectrochim. Acta A, 1972, vol. 28, p. 1529.

    Google Scholar 

  6. Sintez kompleksnykh soedinenii metallov platinovoi gruppy: spravochnik (Synthesis of the Complex Compounds of Platinum Group Metals: a Handbook), Chernyaev, I.I., Ed., Moscow: Nauka, 1964, p. 251.

    Google Scholar 

  7. Fine, D.A., Inorg. Chem., 1969, vol. 8, no. 4, p. 1014.

    Google Scholar 

  8. Venediktov, A.B., Fedotov, M.A., and Korenev, S.V., Koord. Khim., 1999, vol. 25, no. 4, p. 285.

    Google Scholar 

  9. Sinitsyn, N.M., Borisov, V.V., and Kozlov, A.S., Zh. Neorg. Khim., 1982, vol. 27, no. 9, p. 2322.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Siberian Division, Russian Academy of Sciences, Institute of Inorganic Chemistry, pr. Akademika Lavrenteva 3, Novosibirsk, 6300900, Russia

    A. I. Gubanov, S. V. Korenev, A. B. Venediktov & I. P. Asanov

Authors
  1. A. I. Gubanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. A. Gromilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Korenev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. B. Venediktov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. P. Asanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gubanov, A.I., Gromilov, S.A., Korenev, S.V. et al. Synthesis and Study of Potassium Hexabromoiridate(IV). Russian Journal of Coordination Chemistry 28, 864–866 (2002). https://doi.org/10.1023/A:1021638429901

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1021638429901

Keywords

Search

Navigation