Abstract
The purpose of this work was the selective precipitation of Mo(VI) with a,a"-bipyridine and 1,10-phenanthroline. This precipitation, not reported in the literature, was used for the separation of molybdenum from the elements co-eluted from an alumina microspheres column. The alumina had been loaded using a nitric acid solution from the dissolution of a U-Al target. The emphasis was placed on the Mo(VI) separation from ruthenium, tellurium and iodine, all of them were eluted as a group of anionic complexes from the alumina column.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
F. M. S. CARVALHO, A. ABRÃO, J. Radioanal. Nucl. Chem., 218 (1997) 259.
E. M. SCADDEN, Nucleonics, 15 (1957) No. 4, 102.
E. A. C. CROUCH, G. B. COOK, J. Inorg. Nucl. Chem., 2 (1956) 223.
W. L. CHENG, C. S. LEE, C. C. CHEN, V. M. WANG, G. TING, Appl. Radiation Isotopes, 40 (1989) 315.
N. BLAGOJEVIC, R. E. BOYD, E. L. R. HIETHERINGTON, Intern. J. Appl. Radiation Isotopes, 36 (1985) 85.
C. K. SIVARAMAKRISHNAN, A. V. JADHAV, K. RAGHURAMAN, S. RAMAN, P. S. NAIR, M. V. RAMANIAH, Preparation of High Purity Fission Produced Molybdenum-99, BARC-847, 1976.
H. J. HOENES, K. G. STONE, Talanta, 4 (1960) 250.
F. BASOLO, J. C. HAYES, H. M. NEUMANN, J. Am. Chem. Soc., 76 (1954) 3807.
C. CRENTZ, M. CHOU, T. L. NETZEL, M. OKUMURA, N. SUTIN, J. Am. Chem. Soc., 102 (1980) 1309.
E. AMOUYAL, A. HOMSI, J. Chem. Soc. Dalton Trans., 1841 (1990).
J. K. NAGLE, J. S. BERNSTEIN, R. C. YOUNG, T. J. MEYER', Inorg. Chem., 20 (1981) 1760.
L. E. BENNETT, H. TAUBE, Inorg. Chem., 7 (1968) 254.
R. G. PEARSON, O. A. GANSOW, Inorg. Chem., 7 (1968) 1373.
E. KONIG, S. HERZOG, J. Nucl. Chem., 32 (1970) 585.
F. BASOLO, J. C. HAYES, H. M. NEUMANN, J. Am. Chem. Soc., 75 (1953) 5102.
E. KONIG, S. HERZOG, J. Inorg. Nucl. Chem., 32 (1970) 613.
U. DHINGRA, L. R. KAKKAR, Analyst, 113 (1988) 675.
A. S. KOMAROVSKII, N. S. POLUEKTOV, Mikrochim. Acta, 1 (1937) 264.
J. GILLIS, Mikrochim. Acta, 31 (1943) 58.
E. B. SANDELL, Colorimetric Determination of Traces of Metals, Interscience Publishers, Inc., New York, N.Y., 1944.
F. M. S. CARVALHO, E. A. ABRÃO, Anais da Assoc. Bras. Quím., 44 (1995) No. 2, 1.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Carvalho, F.M.S., Abrão, A. Selective precipitation of Mo(VI) with a,a"-bypiridineand 1,10-phenanthroline: Application to molybdenum and radiomolybdenum chemistry. Journal of Radioanalytical and Nuclear Chemistry 254, 633–636 (2002). https://doi.org/10.1023/A:1021627113405
Issue Date:
DOI: https://doi.org/10.1023/A:1021627113405