Abstract
The material of the sacrificial anode has a substantial effect on the nature and yield of the target products of electrochemical phosphorylation of organic halides by white phosphorus in the presence of the nickel complexes with 2,2"-bipyridine. The use of the zinc anode results in the products with tricoordinated phosphorus, viz., triorganylphosphines, the reaction on the aluminum anode affords triorganylphosphine oxides, and the presence of Mg2+ ions in the reaction mixture provides the transformation of white phosphorus into cyclic phosphines (PhP)5.
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Yakhvarov, D.G., Budnikova, Y.H., Tazeev, D.I. et al. The influence of the sacrificial anode nature on the mechanism of electrochemical arylation and alkylation of white phosphorus. Russian Chemical Bulletin 51, 2059–2064 (2002). https://doi.org/10.1023/A:1021611926712
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DOI: https://doi.org/10.1023/A:1021611926712