Abstract
The effects of the polarization of nuclei in photolysis of solid solutions of peroxides of acetylpropionyl and acetylbenzoyl, acetone, acetone‐d 6, methyl ethyl ketone, cyclopentane, and cyclohexanone in cyclohexane and cyclohexane‐d 12 are investigated. The role of the triplet states of the compounds absorbing light and of the radicals formed of them in creation of nonequilibrium polarization of the 1H and 13C nuclei in irradiation of these solutions has been evaluated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
A. L. Buchachenko, R. Z. Sagdeev, and K. M. Salikhov, Magnetic and Spin Effects in Chemical Reactions [inRussian], Novosibirsk (1978).
E. D. Skakovskii, L. Yu. Tychinskaya, V. L. Murashko, and E. M. Usholik, in: Ext. Abstr. of Papers Presentedat XII All-Union School-Symp. "Magnetic Resonance" [in Russian], Kungur (1991), pp. 125–126.
A. A. Obynochnyi, A. G. Mar'yasov, P. A. Purtov, K. M. Salikhov, and Yu. N. Molin, Dokl. Ross. Akad. Nauk,337, No. 4, 479–482 (1994).
M. G. Zysmilich and A. McDermott, J. Am. Chem. Soc., 116, 8362–8363 (1994).
M. G. Zysmilich and A. McDermott, Proc. Natl. Acad. Sci. USA, 93, No. 14, 6857–6860 (1996).
M. G. Zysmilich and A. McDermott,J. Am. Chem. Soc., 118, No. 25, 5867–5873 (1996).
J. Gunnar, J. Am. Chem. Soc., 120, No. 18, 4425–4429 (1998).
C. Blätter, F. Jent, and H. Paul, Chem. Phys. Lett., 166, No. 4, 375–380 (1990).
E. P. Andrew, Nuclear Magnetic Resonance [Russian translation], Moscow (1957).
P. L. Műller-Remmers, P. C. Mishra, and K. Jug, J. Am. Chem. Soc., 106, No. 9, 2538–2543 (1984).
A. V. Yurkovskaya, A. A. Obynochny, and R. Z. Sagdeev, Chem. Phys. Lett., 104, Nos. 2-3, 284–289 (1984).
N. M Ivanova and B. F. Minaev, in: Physicochemical Study of the Structure and Reactivity of Substance [inRussian], Karaganda (1988), pp. 8–14.
J. C. Dalton, K. Dawes, N. J. Turro, D. S. Weiss, J. A. Barltrop, and J. D. Coyle, J. Am. Chem. Soc., 93, No. 23, 7213–7221 (1971).
G. L. Closs and C. E. Doubleday, J. Am. Chem. Soc., 94, No. 26, 9248–9249 (1972).
A. L. Buchachenko, Complexes of Radicals and Molecular Oxygen with Organic Molecules [in Russian], Moscow(1984).
A. A. Obynochny, R. Z. Sagdeev, K. M. Salikhov, S. A. Sukhenko, and A. V. Yurkovskaya, Chem. Phys., 104,415–419 (1986).
K. Tominaga, S. Yamauchi, and N. Hirota, J. Phys. Chem., 95, No. 9, 3671–3676 (1991).
K. Tominaga, S. Yamauchi, and N. Hirota, J. Chem. Phys., 88, No. 2, 553–562 (1988).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Skakovskii, E.D., Shirokii, O.V., Tychinskaya, L.Y. et al. Nonequilibrium Polarization of Nuclei In Photolysis of Solid Cyclohexane Solutions of Diacyl Peroxides and Ketones. Journal of Applied Spectroscopy 69, 689–694 (2002). https://doi.org/10.1023/A:1021596610647
Issue Date:
DOI: https://doi.org/10.1023/A:1021596610647