Abstract
The viscosity η for binary mixtures of methyl acetate (MA), ethyl acetate (EA), n-amyl acetate (nAA), isoamyl acetate (iAA), decyl acetate (DeA), and dodecyl acetate (DoA) with hexane and of MA, EA, nAA, and iAA with tetrachloromethane and trichloromethane has been measured at 303.15 K over the entire range of composition. The viscosity data have been correlated with the equations of Grunberg and Nissan; Hind, McLaughlin, and Ubbelohde; Tamura and Kurata; Katti and Chaudhri; McAllister; Heric and Brewer; and Auslaender. The viscosity deviations Δη and excess Gibbs energy of activation ΔG*E of viscous flow based on Eyring's theory have been calculated. The results have been analyzed in terms of disruption of dipolar association of alkyl acetate and molecular interaction between alkyl acetate and chloromethane.
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REFERENCES
S. L. Oswal and I. N. Patel, Fluid Phase Equil. 149:249 (1998).
S. L. Oswal, P. Oswal, and J. P. Dave, Fluid Phase Equil. 98:225 (1994).
L. Ubbelohde, Ind. Eng. Chem. Anal. Educ. 9:85 (1937).
F. A. Goncalves, J. Kestin, and J. V. Sengers, Int. J. Thermophys. 12:1013 (1991).
J. A. Riddick, W. B. Bunger, and T. K. Sakano, Organic Solvents: Physical Properties and Method of Purifications, 4th ed. (Wiley Interscience, New York, 1986).
S. L. Oswal and A. T. Patel, Int. J. Thermophys. 12:821 (1991).
S. Glasstone, K. J. Laidler, and H. Eyring, The Theory of Rate Process (McGraw-Hill, New York, 1941), p. 514.
J. B. Irving, Viscosity of Liquid Mixtures, NEL Report Nos. 630 and 631 (National Engineering Laboratory, East Kilbride, Glasgow, 1977).
R. C. Reid, J. M. Prausnitz, and B. E. Poling, The Properties of Gases and Liquids, 4th ed. (McGraw-Hill, New York, 1987).
L. Grunberg and A. H. Nissan, Nature 164:799 (1949).
M. Tamura and M. Kurata, Bull. Chem. Soc. Japan 25:32 (1952).
R. K. Hind, E. McLaughlin, and A. R. Ubbelohde, Trans. Faraday Soc. 56:328 (1960).
P. K. Katti and M. M. Chaudhri, J. Chem. Eng. Data 9:442 (1964).
R. A. McAllister, AIChE J. 6:427 (1960).
E. L. Heric and J. C. Brewer, J. Chem. Eng. Data 12:574 (1967).
G. Auslaender, Br. Chem. Eng. 10:196 (1965).
R. J. Bearman and P. F. Jones, J. Chem. Phys. 33:1432 (1960).
I. C. Wei and R. L. Rowley, J. Chem. Eng. Data 29:332 (1984).
S. L. Oswal and M. V. Rathnam, Can. J. Chem. 62:2851 (1984).
S. L. Oswal and J. P. Dave, Int. J. Thermophys. 13:943 (1978).
O. Dusart, C. Piekarski, and S. Piekarski, Chimie. Phys. 75:919 (1978).
J.-P. E. Grolier, D. Ballet, and A. Viallard, J. Chem. Thermodyn. 6:895 (1974).
T. Nakagawa, J. Mol. Liquids 63:303 (1995).
O. Dusart, J.-P. E. Grolier, and A. Viallard, Bull. Soc. Chim. Fr. 587 (1977).
S. L. Oswal and I. N. Patel, Indian J. Chem. Sect. A 29:870 (1990).
R. J. Fort and W. R. Moore, Trans. Faraday Soc. 62:1112 (1966).
R. K. Nigam and B. S. Mahl, Indian J. Chem. 9:1255 (1971).
T. Ohta, H. Asono, and I. Nagata, Fluid Phase Equil. 4:105 (1980).
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Oswal, S.L., Dave, J.P. & Patel, I.N. Viscosity of Binary Mixtures of Alkyl Acetates with Hexane, Tetrachloromethane, and Trichloromethane. International Journal of Thermophysics 20, 1449–1465 (1999). https://doi.org/10.1023/A:1021441122016
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DOI: https://doi.org/10.1023/A:1021441122016