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Synthesis and crystal structures of supramolecular adducts of molybdenum and tungsten selenide aqua complexes with macrocyclic cavitand cucurbituril

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Abstract

The supramolecular compounds {[W3Se4Cl3(H2O)6]2[PyH⊂C36H36N24O12]}Cl3·18H2O (1) and {[Cl3SnMo3Se4Cl3(H2O)6][Cl3SnMo3Se4Cl2(H2O)7](C36H36N24O12)}Cl·26H2O (2) were isolated from solutions of the selenium-containing tungsten and molybdenum clusters [W3Se4(H2O)9]4+ and [Cl3SnMo3Se4(H2O)9]3+, respectively, and organic cavitand cucurbituril. X-ray diffraction analysis demonstrated that the macrocylcic cucurbituril molecule is coordinated on both sides by the cluster cations through the formation of complementary hydrogen bonds. Compound 1 has a chain structure stabilized by Se...Se interactions between the adjacent cluster cores. In compound 2, the bridging μ2-selenium atoms of the cluster fragment Mo3Se4 are coordinated to the tin atom of the SnCl3 – ligand, thus losing the ability to be involved in Se...Se interactions.

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Authors and Affiliations

  1. Siberian Branch of the Russian Academy of Sciences, Institute of Inorganic Chemistry, 3 prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    O. A. Gerasko, A. V. Virovets, M. N. Sokolov, D. N. Dybtsev & V. P. Fedin

  2. Institute of Chemistry of the Far-Eastern Division of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022, Vladivostok, Russian Federation

    A. V. Gerasimenko

  3. Institüt für Anorganishe Chemie, Universität Karlsruhe, 30.45 Engesserstraße Geb., 76128, Karlsruhe, Germany

    D. Fenske

Authors
  1. O. A. Gerasko
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  2. A. V. Virovets
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  3. M. N. Sokolov
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  4. D. N. Dybtsev
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  5. A. V. Gerasimenko
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  6. D. Fenske
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  7. V. P. Fedin
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Gerasko, O.A., Virovets, A.V., Sokolov, M.N. et al. Synthesis and crystal structures of supramolecular adducts of molybdenum and tungsten selenide aqua complexes with macrocyclic cavitand cucurbituril. Russian Chemical Bulletin 51, 1800–1805 (2002). https://doi.org/10.1023/A:1021383914533

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