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Synthesis of α,ω-dichloropermethyloligosilanes by reactions of polydimethylsilane with metal chlorides

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Abstract

The reactions of high-molecular-weight polydimethylsilane with metal chlorides in variable oxidation states at high temperature in the absence of a solvent afford mixtures of α,ω-dichloropermethyloligosilanes Cl(Me2Si) m Cl (m= 2—9). The influence of the reaction conditions (temperature, reaction time, and the reagent ratio) on the composition and yields of the reaction products was examined.

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Authors and Affiliations

  1. Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. I. Chernyavskii & N. A. Chernyavskaya

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  1. A. I. Chernyavskii
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  2. N. A. Chernyavskaya
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Chernyavskii, A.I., Chernyavskaya, N.A. Synthesis of α,ω-dichloropermethyloligosilanes by reactions of polydimethylsilane with metal chlorides. Russian Chemical Bulletin 51, 1751–1753 (2002). https://doi.org/10.1023/A:1021376210839

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