Abstract
The reaction of Cs3[Re6Se7BrBr6] with aqueous ammonia afforded the octahedral rhenium ammine cluster complex cation [Re6Se7Br(NH3)6]3+. This cation crystallized as the [Re6Se7Br(NH3)6][Re6Se7BrBr6]·12H2O compound. The crystal structure of this compound was established. The presence of the NH3 ligands in the coordination environment about the Re atom was confirmed by thermogravimetry, vibrational spectroscopy, and high-resolution mass spectrometry. The resulting compound is the first example of salts composed of the cluster cation and cluster anion possessing the same {Re6Se7Br} cluster core.
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Mironov, Y.V., Naumov, N.G., Yarovoi, S.S. et al. First example of the cluster ammine complex [Re6Se7Br(NH3)6]3+: synthesis and structure of the [Re6Se7Br(NH3)6][Re6Se7BrBr6]·12H2O salt. Russian Chemical Bulletin 51, 1919–1923 (2002). https://doi.org/10.1023/A:1021368905872
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DOI: https://doi.org/10.1023/A:1021368905872