Abstract
An unusual reaction of diaminogermylene and diaminostannylene with sterically hindered phenols which leads to the formation of stable phenoxyl radicals in high concentrations was found. The reaction mechanism was proposed. Amides [(Me3Si)2N]2E (E = Ge, Sn) were investigated electrochemically.
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Orlov, I.S., Moiseeva, A.A., Butin, E.P. et al. A new method for the generation of stable phenoxyl radicals by the reaction of [(Me3Si)2N]2E (E = Ge, Sn) with sterically hindered phenols. Russian Chemical Bulletin 51, 1961–1962 (2002). https://doi.org/10.1023/A:1021341627253
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DOI: https://doi.org/10.1023/A:1021341627253