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Nanoporous Crystalline Material CsLiB6O10

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Abstract

CsLiB6O10 crystals up to 60 × 40 × 20 mm in dimensions were prepared by top-seeded solution growth, and their interaction with water was studied. The crystals were found to be subject to hydration followed by hydrolysis, during which water leaches Cs from the structural channels to yield Cs2B10O16 · 8H2O as the final product. The channel dimensions are not large enough to incorporate ethanol or acetone molecules.

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REFERENCES

  1. Mori, Y., Kuroda, I., Nakajima, S., et al., New Nonlinear Optical Crystal: Cesium Lithium Borate, Appl. Phys. Lett., 1995, vol. 67, pp. 1818–1820.

    Google Scholar 

  2. Mori, Y., Kuroda, I., Nakajima, S., et al., Growth of a Non-Linear Optical Crystal: Cesium Lithium Borate, J. Cryst. Growth, 1995, vol. 156, pp. 307–309.

    Google Scholar 

  3. Sasaki, T., Mori, Y., Kuroda, I., et al., Caesium Lithium Borate: A New Nonlinear Optical Crystal, Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1995, vol. 51, no. 11, pp. 2222–2224.

    Google Scholar 

  4. Takei, H., Suzuki, T., Mamiya, M., et al., Thermal Expansions of Pure and Al-Doped CsLiB6O10 Crystals for Nonlinear Optical Applications, Jpn. J. Appl. Phys., 1997, vol. 36, pp. 126–128.

    Google Scholar 

  5. Taguchi, A., Miyamotoi, A., Mori, Y., et al., Effects of the Moisture on CLBO, Adv. Solid State Lasers, 1997, vol. 10, pp. 19–23.

    Google Scholar 

  6. Pyl'neva, N.A., Kononova, N.G., Danilov, V.I., et al., RF Patent 97105310/25, Byull. Izobret., 1998, no. 28.

  7. Yap, Y.K., Inoue, T., Sakai, H., et al., Long-Term Operation of CsLiB6O10 at Elevated Crystal Temperature, Opt. Lett., 1998, vol. 23, no. 3, pp. 34–36.

    Google Scholar 

  8. Pylneva, N.A., Kononova, N.G., Yurkin, A.M., et al., Top-Seeded Solution Growth of CLBO Crystals, Proc. SPIE-Int. Soc. Opt. Eng., 1999, vol. 3610, pp. 148–155.

    Google Scholar 

  9. Kaplun, A.B. and Meshalkin, A.B., Crystallization of Lithium, Cesium, and Lithium Cesium Triborates in the Li2O-Cs2O-B2O3 System, IX Natsional'naya konferentsiya po rostu kristallov (IX Natl. Conf. on Crystal Growth), Moscow: 2000, p. 450.

  10. Yurkin, A.M., Growth and Properties of Lithium, Lithium Cesium, and Barium Borate Crystals Cand. Sci. (Eng.) Dissertation, Ulan-Ude. 2001.

  11. Isaenko, L., Gubenko, L., Merkulov, A., et al., The Real Structure and the Hydration Processes of Non-Linear Optical Crystal CLBO, 13th Int. Conf. on Crystal Growth, Kyoto, 2001, p. 235.

  12. Kokh, A.E., Kononova, N.G., Lisova, I.A., and Muraviov, S.V., CsLiB6O10 Crystal: Fourth and Fifth-Harmonic Generation in Nd:YAP Laser, Proc. SPIE-Int. Soc. Opt. Eng., 2001, vol. 4268, pp. 43–48.

    Google Scholar 

  13. Powder Diffraction File, Swarthmore: Joint Committee on Powder Diffraction Standards, Data Card 50-368.

  14. Powder Diffraction File, Swarthmore: Joint Committee on Powder Diffraction Standards, Data Card 22-0175.

  15. Chen, C., Wu, Y., and Li, R., The Development of New NLO Crystals in the Borate Series, J. Cryst. Growth, 1990, vol. 99, pp. 790–798.

    Google Scholar 

  16. Zeolite Chemistry and Catalysis, Rabo, J. A., Ed., Washington DC: American Chemical Society, 1976. Translated under the title Khimiya tseolitov i kataliz na tseolitakh, Moscow: Mir, 1980, vol. 1.

    Google Scholar 

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Kononova, N.G., Kokh, A.E., Fedorov, P.P. et al. Nanoporous Crystalline Material CsLiB6O10 . Inorganic Materials 38, 1264–1269 (2002). https://doi.org/10.1023/A:1021327622149

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