Abstract
CsLiB6O10 crystals up to 60 × 40 × 20 mm in dimensions were prepared by top-seeded solution growth, and their interaction with water was studied. The crystals were found to be subject to hydration followed by hydrolysis, during which water leaches Cs from the structural channels to yield Cs2B10O16 · 8H2O as the final product. The channel dimensions are not large enough to incorporate ethanol or acetone molecules.
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REFERENCES
Mori, Y., Kuroda, I., Nakajima, S., et al., New Nonlinear Optical Crystal: Cesium Lithium Borate, Appl. Phys. Lett., 1995, vol. 67, pp. 1818–1820.
Mori, Y., Kuroda, I., Nakajima, S., et al., Growth of a Non-Linear Optical Crystal: Cesium Lithium Borate, J. Cryst. Growth, 1995, vol. 156, pp. 307–309.
Sasaki, T., Mori, Y., Kuroda, I., et al., Caesium Lithium Borate: A New Nonlinear Optical Crystal, Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1995, vol. 51, no. 11, pp. 2222–2224.
Takei, H., Suzuki, T., Mamiya, M., et al., Thermal Expansions of Pure and Al-Doped CsLiB6O10 Crystals for Nonlinear Optical Applications, Jpn. J. Appl. Phys., 1997, vol. 36, pp. 126–128.
Taguchi, A., Miyamotoi, A., Mori, Y., et al., Effects of the Moisture on CLBO, Adv. Solid State Lasers, 1997, vol. 10, pp. 19–23.
Pyl'neva, N.A., Kononova, N.G., Danilov, V.I., et al., RF Patent 97105310/25, Byull. Izobret., 1998, no. 28.
Yap, Y.K., Inoue, T., Sakai, H., et al., Long-Term Operation of CsLiB6O10 at Elevated Crystal Temperature, Opt. Lett., 1998, vol. 23, no. 3, pp. 34–36.
Pylneva, N.A., Kononova, N.G., Yurkin, A.M., et al., Top-Seeded Solution Growth of CLBO Crystals, Proc. SPIE-Int. Soc. Opt. Eng., 1999, vol. 3610, pp. 148–155.
Kaplun, A.B. and Meshalkin, A.B., Crystallization of Lithium, Cesium, and Lithium Cesium Triborates in the Li2O-Cs2O-B2O3 System, IX Natsional'naya konferentsiya po rostu kristallov (IX Natl. Conf. on Crystal Growth), Moscow: 2000, p. 450.
Yurkin, A.M., Growth and Properties of Lithium, Lithium Cesium, and Barium Borate Crystals Cand. Sci. (Eng.) Dissertation, Ulan-Ude. 2001.
Isaenko, L., Gubenko, L., Merkulov, A., et al., The Real Structure and the Hydration Processes of Non-Linear Optical Crystal CLBO, 13th Int. Conf. on Crystal Growth, Kyoto, 2001, p. 235.
Kokh, A.E., Kononova, N.G., Lisova, I.A., and Muraviov, S.V., CsLiB6O10 Crystal: Fourth and Fifth-Harmonic Generation in Nd:YAP Laser, Proc. SPIE-Int. Soc. Opt. Eng., 2001, vol. 4268, pp. 43–48.
Powder Diffraction File, Swarthmore: Joint Committee on Powder Diffraction Standards, Data Card 50-368.
Powder Diffraction File, Swarthmore: Joint Committee on Powder Diffraction Standards, Data Card 22-0175.
Chen, C., Wu, Y., and Li, R., The Development of New NLO Crystals in the Borate Series, J. Cryst. Growth, 1990, vol. 99, pp. 790–798.
Zeolite Chemistry and Catalysis, Rabo, J. A., Ed., Washington DC: American Chemical Society, 1976. Translated under the title Khimiya tseolitov i kataliz na tseolitakh, Moscow: Mir, 1980, vol. 1.
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Kononova, N.G., Kokh, A.E., Fedorov, P.P. et al. Nanoporous Crystalline Material CsLiB6O10 . Inorganic Materials 38, 1264–1269 (2002). https://doi.org/10.1023/A:1021327622149
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DOI: https://doi.org/10.1023/A:1021327622149