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Synthesis and crystal structure of the nanosized supramolecular SmIII complex with macrocyclic cavitand cucurbituril {[Sm(H2O)4]2(C36H36N24O12)3}Br6·44H2O

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Abstract

The supramolecular compound {[Sm(H2O)4]2(Cuc)3}Br6·44H2O (Cuc = C36H36N24O12) was synthesized. Its crystal and molecular structure was established by X-ray diffraction analysis. The binuclear complex cation {(Cuc)[Sm(H2O)4](Cuc)[Sm(H2O)4](Cuc)}6+ built from the alternating cucurbituril molecules (C36H36N24O12) and the [Sm(H2O)4]3+ aqua ions is a triple-decker nanosized (33 Å) sandwich.

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Authors and Affiliations

  1. Siberian Branch of the Russian Academy of Sciences, Institute of Inorganic Chemistry, 3 Prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    D. G. Samsonenko, O. A. Gerasko & V. P. Fedin

  2. Russian Academy of Sciences, G. A. Razuvaev Institute of Organometallic Chemistry, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    J. Lipkowski

  3. Polish Academy of Sciences, Institute of Physical Chemistry, 44/52 Kasprzaka, Warsaw, Poland

    A. V. Virovets

Authors
  1. D. G. Samsonenko
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  2. O. A. Gerasko
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  3. J. Lipkowski
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  4. A. V. Virovets
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  5. V. P. Fedin
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Samsonenko, D.G., Gerasko, O.A., Lipkowski, J. et al. Synthesis and crystal structure of the nanosized supramolecular SmIII complex with macrocyclic cavitand cucurbituril {[Sm(H2O)4]2(C36H36N24O12)3}Br6·44H2O. Russian Chemical Bulletin 51, 1915–1918 (2002). https://doi.org/10.1023/A:1021316921801

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  • DOI: https://doi.org/10.1023/A:1021316921801

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