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Ruthenium(II) carbonyl complexes containing tridentate Schiff bases

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Abstract

New ruthenium(II) complexes, [Ru(CO)(B)(LL′)(PPh3)] (where, LL′ = tridentate Schiff bases; B = PPh3, pyridine, piperidine or morpholine) have been prepared by reacting [RuHCl(CO)(PPh3)3] or [RuHCl(CO)(PPh3)2(B)] with Schiff bases containing donor groups (O, N, X) viz., salicylaldehyde thiosemicarbazone (X = S), salicylaldehyde semicarbazone (X = O), o-hydroxyacetophenone thiosemicarbazone (X = S) and o-hydroxyacetophenone semicarbazone (X = O). The new complexes were characterised by elemental analysis, spectral (i.r., 1H- and 31P-n.m.r.), data.

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  1. Department of Chemistry, Bharathiar University, Coimbatore, 641 046, India

    Thangaian D. Thangadurai & Karuppannan Natarajan

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  1. Thangaian D. Thangadurai
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  2. Karuppannan Natarajan
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Thangadurai, T.D., Natarajan, K. Ruthenium(II) carbonyl complexes containing tridentate Schiff bases. Transition Metal Chemistry 27, 840–843 (2002). https://doi.org/10.1023/A:1021310829414

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