Abstract
Iron halide species were produced by the reaction of laser-evaporated iron atoms with halogen-containing reactant gas, and isolated in low-temperature matrices to obtain their Mössbauer spectra. Iron fluoride (Fe2F6, FeF3 and Fe2F4) and iron iodide (FeI2 and Fe2I4) were produced by the reaction of laser-evaporated iron atoms with sulfur hexafluoride SF6 and methyl iodide CH3I, respectively. The yields of the products varied depending on the concentration of reactant gas in the Ar matrix. Molecular orbital calculations were performed in order to confirm their assignments.
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Yamada, Y. Iron Halide Species Produced by Laser-Evaporation. Hyperfine Interactions 139, 77–85 (2002). https://doi.org/10.1023/A:1021223405729
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DOI: https://doi.org/10.1023/A:1021223405729