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In situ 57Fe Mössbauer Investigation of Solid-State Redox Reactions of Lithium Insertion Electrodes for Advanced Batteries

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Abstract

A novel in situ electrochemical cell for 57Fe Mössbauer measurements was developed in order to clarify the mechanisms of solid-state redox reactions in lithium insertion materials containing iron. Our in situ Mössbauer technique was successfully applied to the determination as to which transition metal ion was a redox center in the insertion electrodes, such as LiFe0.5Mn1.5O4, LiFeTiO4, or LiFe0.25Ni0.75O2, for the lithium-ion batteries.

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Authors and Affiliations

  1. Department of Chemistry, Daido Institute of Technology, 10-3 Takiharu-cho, Minami-ku, Nagoya, 457-8530, Japan

    Yoichi Sakai

  2. Department of Applied Chemistry, Graduate School of Engineering, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi, Osaka, 558-8585, Japan

    Kingo Ariyoshi & Tsutomu Ohzuku

Authors
  1. Yoichi Sakai
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  2. Kingo Ariyoshi
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  3. Tsutomu Ohzuku
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Sakai, Y., Ariyoshi, K. & Ohzuku, T. In situ 57Fe Mössbauer Investigation of Solid-State Redox Reactions of Lithium Insertion Electrodes for Advanced Batteries. Hyperfine Interactions 139, 67–76 (2002). https://doi.org/10.1023/A:1021219304820

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  • DOI: https://doi.org/10.1023/A:1021219304820

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