Skip to main content
SpringerLink
Log in

Mössbauer, X-ray, electrical and magnetic properties of lithium borosilicate glasses containing iron and manganese Part I. Mössbauer measurements

  • Published:
Czechoslovak Journal of Physics Aims and scope

Abstract

The effect of the replacement of MnO2 by Fe2O3 on the oxidation states of iron in some lithium borosilicate glasses were studied using Mössbauer spectroscopy. DTA and infrared measurements showed the presence of two glassy phases, one of them containing iron and the other manganese. The Mössbauer spectra were measured at room temperature for all the glass samples. The spectra revealed the presence of Fe ions only in ferric state in both tetrahedral and octahedral coordination. Also, it was observed that the ratio between the number of iron ions in both coordination states has not changed with the increase of MnO2 content.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Nishida T, Hirai T., and Takashima Y.: Phys. Chem. Glasses22 (1981) 94.

    Google Scholar 

  2. Kashif I., Farouk H., Sanad A.M., Aly S.A., and Farhan H.: Phys. Chem. Glasses32 (1991) 3.

    Google Scholar 

  3. Toragin M.P. and Eisenstein J.C.: J. Non-Cryst. Solids3 (1970) 311.

    Article  Google Scholar 

  4. Labor Ch. and Gielen P.: J. Non-Cryst. Solids13 (1974) 107.

    Article  Google Scholar 

  5. Bukrey R.R., Kenealy P.E., Beard G.B., and Hooper H.O.: Phys. Review B9 (1974) 1052.

    Article  ADS  Google Scholar 

  6. Raman T., Rao G.N., and Chakravort D.: J. Non-Cryst. Solids29 (1978) 85.

    Article  Google Scholar 

  7. Sekhan S.S. and Kamel R.: J. Non-Cryst. Solids28 (1978) 189.

    Article  Google Scholar 

  8. Kashif I., Gomaa S.Sh., Mostafa A.G., Hamad S.M., and Sanad A.M.: Phys. Chem. Glasses29 (1988) 72.

    Google Scholar 

  9. Soliman A.A., Farouk H., Aly S.A., Kashif I., and Sanad A.M. (to be published in J. Material Sci. Eng. B).

Download references

Author information

Authors and Affiliations

  1. Physics Department, Faculty of Science, Al-Azhar University, 11884, Nasr-city, Cairo, Egypt

    A. A. Soliman, H. Farouk, I. Kashif & A. M. Sanad

  2. Physics Department, Faculty of Girls, Ain Shams University, Cairo, Egypt

    A. A. Soliman

Authors
  1. A. A. Soliman
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Farouk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. Kashif
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. M. Sanad
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Soliman, A.A., Farouk, H., Kashif, I. et al. Mössbauer, X-ray, electrical and magnetic properties of lithium borosilicate glasses containing iron and manganese Part I. Mössbauer measurements. Czech J Phys 47, 553–558 (1997). https://doi.org/10.1023/A:1021215608367

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1021215608367

Keywords

Search

Navigation