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High-Temperature Spectroscopy of Organometallics: The Gol'danskii–Karyagin Effect in Ferrocene Complexes

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Abstract

The temperature dependence of the mean-square-amplitude of vibration and the motional anisotropy of the metal atom in a number of structurally related organometallics has been examined in detail and can be related to the molecular level architecture of these solids. In particular, it is noted that in octamethylferrocenylmethanol, there is a competition between the “gear-wheel effect” observed in related octamethylferrocenyl complexes and hydrogen bonding between neighboring molecules in the solid below the melting point.

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References

  1. Nowik, I. and Herber, R. H., Inorg. Chim. Acta 310 (2000), 191; Herber, R. H. and Nowik, I., Hyp. Interact. 126 (2000), 127; and references therein.

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Authors and Affiliations

  1. Racah Institute of Physics, The Hebrew University, Jerusalem, 91904, Israel

    Rolfe H. Herber & Israel Nowik

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  1. Rolfe H. Herber
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  2. Israel Nowik
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Herber, R.H., Nowik, I. High-Temperature Spectroscopy of Organometallics: The Gol'danskii–Karyagin Effect in Ferrocene Complexes. Hyperfine Interactions 141, 297–301 (2002). https://doi.org/10.1023/A:1021211716349

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  • DOI: https://doi.org/10.1023/A:1021211716349

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