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Synthesis and Structure of Sb-Containing Compounds of Binuclear Phenols

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Abstract

The toluene solvate of 1-(tetraphenylstiboxy)-3-oxybenzene (I) was synthesized by reacting pentaphenylantimony with resorcin (at a molar ratio of 1 : 1) in toluene at 20°C, and the 1 : 3 complex (II)of 1,4-bis(tetraphenylstiboxy)benzene with hydroquinone was synthesized by reacting pentaphenylantimony with hydroquinone (at a molar ratio of 1 : 2) under similar conditions. The structures of the compounds obtained were determined using X-ray diffraction analysis. The Sb atoms in I and II have a distorted trigonal-bipyramidal coordination to the axial phenolate groups.

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Authors and Affiliations

  1. Blagoveshchensk Pedagogical State University, ul. Lenina 104, Blagoveshchensk, 675000, Russia

    V. V. Sharutin, A. P. Pakusina, O. K. Sharutina, O. V. Subacheva, B. V. Bukvetskii, D. Yu. Popov & A. V. Gerasimenko

  2. Russian Academy of Sciences, Institute of Chemistry, Far East Division, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    V. V. Sharutin, A. P. Pakusina, O. K. Sharutina, O. V. Subacheva, B. V. Bukvetskii, D. Yu. Popov & A. V. Gerasimenko

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  1. V. V. Sharutin
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  2. A. P. Pakusina
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  3. O. K. Sharutina
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  4. O. V. Subacheva
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  5. B. V. Bukvetskii
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  6. D. Yu. Popov
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  7. A. V. Gerasimenko
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Sharutin, V.V., Pakusina, A.P., Sharutina, O.K. et al. Synthesis and Structure of Sb-Containing Compounds of Binuclear Phenols. Russian Journal of Coordination Chemistry 28, 761–766 (2002). https://doi.org/10.1023/A:1021198513120

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  • DOI: https://doi.org/10.1023/A:1021198513120

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