Abstract
Effect of supporting cations on the EDL structure is analyzed in the region of specific adsorption of anions. The analysis assumes that cations are pulled into the EDL dense part due to their interaction with specifically-adsorbed anions. The model describing this phenomenon is based on the introduction of a second, cationic IHP situated between the plane where centers of charges of specifically-adsorbed anions are localized and OHP. The adsorption of ions, electrode charge, PZC, and EDL capacitance are calculated using two adsorption isotherms for anions and cations.
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REFERENCES
Nikolaeva-Fedorovich, N.V., Fokina, L.A., and Petrii, O.A., Dokl. Akad. Nauk SSSR, 1958, vol. 122, p. 639.
Frumkin, A.N., Petrii, O.A., and Nikolaeva-Fedorovich, N.V., Dokl. Akad. Nauk SSSR, 1959, vol. 128, p. 1006.
Frumkin, A.N. and Petry, O.A., Nikolaeva-Fedorovich, N.V., Electrochim. Acta, 1963, vol. 8, p. 177.
Susbielles, G.G., Delahay, P., and Solon, E., J. Phys. Chem., 1966, vol. 70, p. 2601.
Baron, B., Delahay, P., and Kelsh, D.J., J. Electroanal. Chem., 1968, vol. 18, p. 184.
Baugh, L.M. and Parsons, R., J. Electroanal. Chem., 1975, vol. 58, p. 229.
Damaskin, B.B. and Baturina, O.A., Elektrokhimiya, 1998, vol. 34, p. 303.
Damaskin, B.B. and Baturina, O.A., Elektrokhimiya, 1998, vol. 34, p. 412.
Damaskin, B.B. and Ivanova, R.V., Elektrokhimiya, 1973, vol. 9, p. 1569.
Palm, U.V. and Damaskin, B.B., Itogi Nauki Tekh., Ser.: Elektrokhimiya, 1977, vol. 12, p. 99.
Rogozhnikov, N.A. and Zakharova, N.M., Elektrokhimiya, 1997, vol. 33, p. 144.
Vaartnou, M.G., Inno, S.K., Salve, M.A., and Palm, U.V., Abstracts of Papers, IV Simpozium “Dvoinoi sloi i adsorbtsiya na tverdykh elektrodakh” (IV Symp. Double Layer and Adsorption on Solid Electrodes), Tartu: Tartus. Gos. Univ., 1975, p. 59.
Damaskin, B., Palm, U., and Vaartnou, M., J. Electroanal. Chem., 1976, vol. 70, p. 103.
Bek, R.Yu., Nechaev, E.A., and Kudryavtsev, N.T., Elektrokhimiya, 1967, vol. 3, p. 1121.
Nechaev, E.A., Bek, R.Yu., and Kudryavtsev, N.T., Elektrokhimiya, 1968, vol. 4, p. 545.
Bek, R.Yu. and Kosolapov, G.V., Sib. Khim. Zh., 1991, no. 3, p. 36.
Bek, R.Yu., Rogozhnikov, N.A., and Kosolapov, G.V., Elektrokhimiya, 1998, vol. 34, p. 1292.
Fawcett, W.R. and McCarrik, T.A., J. Electrochem. Soc., 1976, vol. 123, p. 1325.
Rogozhnikov, N.A., Elektrokhimiya, 1998, vol. 34, p. 1298.
Rogozhnikov, N.A., Elektrokhimiya, 2001, vol. 37, p. 1269.
Adamson, A., The Physical Chemistry of Surfaces, New York: Wiley, 1976.
Parry, J.M. and Parsons, R., Trans. Faraday Soc., 1963, vol. 59, p. 241.
Techniques of Electrochemistry, Yeager, E. and Salkind, A.J., Eds., New York: Wiley Interscience, 1972.
Rogozhnikov, N.A. and Bek, R.Yu., Elektrokhimiya, 1980, vol. 16, p. 662.
Rogozhnikov, N.A. and Bek, R.Yu., Elektrokhimiya, 1988, vol. 24, p. 839.
Grahame, D.C., Z. Electrochem., 1958, vol. 62, p. 264.
Grahame, D.C. and Parsons, R., J. Am. Chem. Soc., 1961, vol. 83, p. 1291.
Wroblowa, H., Kovac, Z., and Bockris, J.O'M., Trans. Faraday Soc., 1965, vol. 61, p. 1523.
Rogozhnikov, N.A. and Bek, R.Yu., Elektrokhimiya, 1996, vol. 32, p. 1444.
Izmailov, N.A., Elektrokhimiya rastvorov (The Electrochemistry of Solutions), Moscow: Khimiya, 1966.
Davies, C.W., The Structure of Electrolytic Solutions, Hamer, W.J., Ed., New York: Wiley, 1959, p. 19.
Delahay, P., Double Layer and Electrode Kinetics, New York: Wiley Interscience, 1965.
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Rogozhnikov, N.A. Effect of Anion-Induced Cation Adsorption on the Electrical Double Layer Structure. Russian Journal of Electrochemistry 38, 1263–1270 (2002). https://doi.org/10.1023/A:1021174431853
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DOI: https://doi.org/10.1023/A:1021174431853