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Synthesis of Polynuclear Organometallic and o-Quinone Compounds by Direct Metal Oxidation in Nonaqueos Solutions

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Abstract

A review of papers concerned with the synthesis of polynuclear organometallic compounds by direct metal oxidation with organoelemental halides is presented. The effect of solvent nature on the rate of metal oxidation in nonaqueous solutions is considered. The mechanism of metal oxidation with o-quinone in aprotic dipolar solvents is suggested.

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  1. Scientific Research Institute of Chemistry, Lobachevskii State University, Nizhnii Novgorod, Russia

    A. V. Piskunov, S. V. Maslennikov, I. V. Spirina & V. P. Maslennikov

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  1. A. V. Piskunov
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Piskunov, A.V., Maslennikov, S.V., Spirina, I.V. et al. Synthesis of Polynuclear Organometallic and o-Quinone Compounds by Direct Metal Oxidation in Nonaqueos Solutions. Russian Journal of Coordination Chemistry 28, 808–815 (2002). https://doi.org/10.1023/A:1021167100824

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