Skip to main content
SpringerLink
Log in

Two-dimensional nickel(II) tetraaza macrocyclic complex linked by hydrogen bonds

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The complex [Ni(L)](PDC) ⋅ 2H2O (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo[16,4, 01.18,07.12]docosane; PDC = 3,5-pyrazoledicarboxylate) has been synthesized and characterized by X-ray crystallography. It crystallizes in the monoclinic system P21/c with a = 9.739(4) Å, b = 10.491(3) Å, c = 16.884(3) Å, β = 97.17(2)°, V = 1711.5(8) Å3, Z = 4. The coordination environment around the nickel(II) ion exhibits a slightly distorted square-plane with four secondary amines of the macrocycle. The title compound is interconnected to give a two-dimensional network through the hydrogen-bonding interactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lehn, J.-M. Supramolecular Chemistry: Concepts and Perspectives; VCH: Weinheim, Germany, 1995.

    Google Scholar 

  2. Lawrence, D.S.; Jiang, T.; Levett, M. Chem. Rev. 1995, 95, 2229.

    Google Scholar 

  3. Bhyrappa, P.; Wilson, S.R.; Suslick, K.S. J. Am. Chem. Soc. 1997, 119, 8492.

    Google Scholar 

  4. Gardner, G.B.; Venkatarama, D.; Moore, J.S.; Lee, S. Nature 1995, 374, 792.

    Google Scholar 

  5. Janiak, C. Angew. Chem., Int. Ed. Engl. 1997, 36, 1431.

    Google Scholar 

  6. Yaghi, O.M.; Li, H.; Groy, T.L. J. Am. Chem. Soc. 1996, 118, 9096.

    Google Scholar 

  7. Subramanian, S.; Zaworotko, M.J. Angew. Chem., Int. Ed. Engl. 1995, 34, 2127.

    Google Scholar 

  8. Fujita, M.; Aoyagi, M.; Ibukuro, F.; Ogura, K.; Yamaguchi, K. J. Am. Chem. Soc. 1998, 120, 611.

    Google Scholar 

  9. Subramanian, S.; Zaworotko, M.J. Coord. Chem. Rev. 1994, 137, 357.

    Google Scholar 

  10. Jorgensen, W.L.; Severance, D.L. J. Am. Chem. Soc. 1990, 112, 4768.

    Google Scholar 

  11. Munakata, M.; Wu, L.P.; Kuroda-Sowa, T. Bull. Chem. Soc. Jpn. 1997, 70, 1727.

    Google Scholar 

  12. Yaghi, O.M.; Li, G.; Li, H. Nature 1995, 378, 703.

    Google Scholar 

  13. Harrison, W.T.A.; Hannooman, L. Angew. Chem., Int. Ed. Engl. 1997, 36, 640.

    Google Scholar 

  14. Carlucci, L.; Ciani, G.; Proserpio, D.M.; Sironi, A. J. Am. Chem. Soc. 1995, 117, 4562.

    Google Scholar 

  15. Choi, H.J.; Suh, M.P. J. Am. Chem. Soc. 1998, 120, 10622.

    Google Scholar 

  16. Kang, S.-G.; Kweon, J.K.; Jung, S.-K. Bull. Korean Chem. Soc. 1991, 12, 483.

    Google Scholar 

  17. Choi, K.-Y.; Kim, J.C.; Jensen, W.P.; Suh, I.-H.; Choi, S.-S. Acta Crystallogr., Sect. C 1996, 52, 2166.

    Google Scholar 

  18. Sheldrick G.M. Acta Crystallogr., Sect. A 1990, 46, 467.

    Google Scholar 

  19. Sheldrick G.M. SHELXL97, Program for the Refinement of Crystal Structures; University of G¨ottingen: Germany, 1997.

    Google Scholar 

  20. Johnson, C.K. ORTEP, A Fortran Thermal Ellipsoid Plot Program; Technical Report No. ORNL-5138; Oak Ridge National Laboratory: USA, 1976.

    Google Scholar 

  21. Ito, T.; Toriumi, K.; Ito, H. Bull. Chem. Soc. Jpn. 1981, 54, 1096.

    Google Scholar 

  22. Henrik, K.; Tasker, P.A.; Lindoy, L.F. Prog. Inorg. Chem. 1985, 33, 1.

    Google Scholar 

  23. Fabbrizzi, L.; Manotti, L.A.; Taglietti, A.; Ugozzoli, F. J. Chem. Soc., Dalton Trans. 1991, 3263.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry Education, Kongju National University, Kongju, 314-701, Korea

    Ki-Young Choi

Authors
  1. Ki-Young Choi
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Choi, KY. Two-dimensional nickel(II) tetraaza macrocyclic complex linked by hydrogen bonds. Journal of Chemical Crystallography 32, 537–540 (2002). https://doi.org/10.1023/A:1021165314529

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1021165314529

Search

Navigation