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Synthesis and Structure of Tetraphenylantimony 2-Furoinate and Benzoate

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Abstract

Tetraphenylantimony 2-furoinate Ph4SbOC(O)C4H3O is synthesized by the reaction of pentaphenyl-antimony with triphenylantimony bis(2-furoinate). The structure of the compound is determined by X-ray diffraction analysis. The Sb atom in the compound has a distorted trigonal-bipyramidal coordination with the phenyl and 2-furoinate groups in the axial positions. The Sb(1)–C(Ph)eq distances lie in the 2.119(1)–2.121(1) Å interval; the Sb–O(1) and Sb–C(Ph)ax bond lengths are equal to 2.273(1) and 2.161(1) Å, respectively; and the Sb(1)···О(2) intramolecular contact is 3.234(1) Å.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia

    V. V. Sharutin, A. P. Pakusina, T. P. Platonova, I. V. Egorova, O. K. Sharutina, A. V. Gerasimenko, A. S. Sergienko & E. A. Gerasimenko

  2. Russian Academy of Sciences, Institute of Chemistry, Far East Division, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    V. V. Sharutin, A. P. Pakusina, T. P. Platonova, I. V. Egorova, O. K. Sharutina, A. V. Gerasimenko, A. S. Sergienko & E. A. Gerasimenko

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  1. V. V. Sharutin
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  2. A. P. Pakusina
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  3. T. P. Platonova
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  4. I. V. Egorova
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  5. O. K. Sharutina
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  6. A. V. Gerasimenko
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  7. A. S. Sergienko
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  8. E. A. Gerasimenko
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Sharutin, V.V., Pakusina, A.P., Platonova, T.P. et al. Synthesis and Structure of Tetraphenylantimony 2-Furoinate and Benzoate. Russian Journal of Coordination Chemistry 28, 753–757 (2002). https://doi.org/10.1023/A:1021165112211

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  • DOI: https://doi.org/10.1023/A:1021165112211

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