Skip to main content
SpringerLink
Log in

Electrochemical Behavior of Intermetallic Compounds of the Type AB5 Synthesized during the Reduction of a Mixture of Oxides and Salts by Lithium Hydride

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

The intermetallic compounds LaNi4.5Co0.2Sn0.3, La0.9Zr0.1Ni4.5Al0.5, Mm0.8Ni4.7Co0.2Sn0.3, Mm0.8Ni4.7Co0.2Ge0.3, MmNi4.5Co0.2Ge0.3, and MmNi4.5Co0.2Sn0.3, which are synthesized by a new method, specifically, during a high-temperature reduction of a mixture of oxides and carbonates by lithium hydride, have high homogeneity and dispersion degree. According to electrochemical charge-discharge tests, electrodes of these compounds ensure a high discharge capacity (∼300 mA h g–1) as early as after the first 2–3 cycles and their behavior is stable and reversible.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Petrii, O.A., Vasina, S.Ya., and Korobov, I.I., Usp. Khim., 1996, vol. 65, p. 195.

    Google Scholar 

  2. Kleperis, J., Wojcik, G., Czerwinski, A., et al., J. Solid State Electrochem., 2001, vol. 5, p. 229.

    Google Scholar 

  3. Kamarzin, A.A., Podoinitsin, S.V., Stonoga, Yu.A., Zelenin, Yu.M., Bondin, Yu.M., and Osadchaya, L.I., RF Patent no. 97105751, Byull. Izobret., 1998, no. 17, p. 236.

  4. Witham, C., Hightower, A., Fultz, B., et al., J. Electrochem. Soc., 1997, vol. 144, p. 3758.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Siberian Division, Russian Academy of Sciences, Institute of Inorganic Chemistry, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090, Russia

    V. V. Sokolov & L. I. Osadchaya

  2. Moscow State University, Vorob'evy gory, Moscow, 119899, Russia

    O. A. Petrii, T. Ya. Safonova, V. N. Verbetskii & T. A. Zotov

Authors
  1. V. V. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. I. Osadchaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. A. Petrii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. Ya. Safonova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. N. Verbetskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. T. A. Zotov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sokolov, V.V., Osadchaya, L.I., Petrii, O.A. et al. Electrochemical Behavior of Intermetallic Compounds of the Type AB5 Synthesized during the Reduction of a Mixture of Oxides and Salts by Lithium Hydride. Russian Journal of Electrochemistry 38, 1260–1262 (2002). https://doi.org/10.1023/A:1021122415015

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1021122415015

Keywords

Search

Navigation