Skip to main content
SpringerLink
Log in

Binuclear Copper(II) Complexes with (1R*,4S*)-1-N-Morpholino-n-menth-8-en-2-one E-oxime: Synthesis, Structure, and Magnetic Properties

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Copper(II) complexes with (1R*,4S*)-1-N-morpholino-n-menth-8-en-4-one (HL), namely, [Cu2(HL)2Cl4] (I) and [Cu2(HL)LCl3] · CH3CN (II), were synthesized and characterized by X-ray diffraction analysis, magnetic susceptibility, and EPR methods. The complexes have binuclear structures. In compound I, the coordination polyhedron of CuCl3N2 is a square pyramid in planar Cu2Cl2 metal cycle; the exchange couplings of unpaired electrons of Cu(II) ions are weak. Complex II incorporates polyhedra of CuCl2N2 (flattened tetrahedron) and of CuCl2N2O (trigonal bipyramid). The Cu2ClNO metal cycle is nonplanar with antiferromagnetic exchange coupling and exchange parameter –2J = 182 cm–1. The EPR spectrum of compound I are analyzed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Tkachev, A.V., Ross. Khim. Zh., 1998, vol. 42, nos. 1-2, p. 42.

    Google Scholar 

  2. Zelewsky von, A. and Mamula, O., J. Chem. Soc., Dalton Trans., 2000, p. 219.

  3. Larionov, S.V., Myachina, L.I., Romanenko, G.V., et al., Koord. Khim., 2001, vol. 27, no. 6, p. 455.

    Google Scholar 

  4. Tkachev, A.V., Denisov, A.Yu., Rukavishnikov, A.V., et al., Aust. J. Chem., 1992, vol. 45, no. 6, p. 1077.

    Google Scholar 

  5. Beckett, R., Colton, R., Hoskins, B.F., et al., Aust. J. Chem., 1969, vol. 22, no. 12, p. 2527.

    Google Scholar 

  6. Colacio, E., Domingues-Vera, J.M., Escuer, A., et al., Inorg. Chem., 1994, vol. 33, no. 18, p. 3914.

    Google Scholar 

  7. Costes, J.-P., Dahan, F., Dupuis, A., and Taurent, J.-P., Inorg. Chem., 2000, vol. 39, no. 2, p. 169.

    Google Scholar 

  8. Costes, J.-P., Dahan, F., and Dupuis, A., Inorg. Chem., 2000, vol. 39, no. 26, p. 5994.

    Google Scholar 

  9. Kalinnikov, V.T. and Rakitin, Yu.V., Vvedenie v magnetokhimiyu. Metod staticheskoi magnitnoi vospriimchivosti v khimii (Introduction to Magnetochemistry: Method of Static Magnetic Susceptibility in Chemistry), Moscow: Nauka, 1980, p. 220.

    Google Scholar 

  10. Bleaney, B. and Bowers, K.D., Proc. R. Soc. London, Ser. A, 1952, vol. 214, no. 3, p. 451.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Russian Academy of Sciences, Institute of Inorganic Chemistry, Siberian Division, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090, Russia

    S. V. Larionov, Z. A. Savel'eva, G. V. Romanenko, A. V. Tkachev, V. N. Ikorskii & E. G. Boguslavskii

  2. Russian Academy of Sciences, Novosibirsk Institute of Organic Chemistry, Siberian Division, pr. Akademika Lavrent'eva 9, Novosibirsk, 630090, Russia

    S. V. Larionov, Z. A. Savel'eva, G. V. Romanenko, A. V. Tkachev, V. N. Ikorskii & E. G. Boguslavskii

Authors
  1. S. V. Larionov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. A. Savel'eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. V. Romanenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Tkachev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. N. Ikorskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. G. Boguslavskii
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Larionov, S.V., Savel'eva, Z.A., Romanenko, G.V. et al. Binuclear Copper(II) Complexes with (1R*,4S*)-1-N-Morpholino-n-menth-8-en-2-one E-oxime: Synthesis, Structure, and Magnetic Properties. Russian Journal of Coordination Chemistry 28, 780–788 (2002). https://doi.org/10.1023/A:1021106914937

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1021106914937

Keywords

Search

Navigation