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Catalyst Design of Pt-Modified Ni/Al2O3 Catalyst with Flat Temperature Profile in Methane Reforming with CO2 and O2

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Abstract

Pt(0.3)/Ni(10)/Al2O3, prepared by a sequential impregnation method, exhibited a more excellent performance in methane reforming with CO2 and O2 in terms of the catalytic activity and the temperature profile of the catalyst bed than Pt(0.3) + Ni(10)/Al2O3 prepared by a coimpregnation method, Ni(10)/Al2O3, Pt(0.3)/Al2O3, and Pt(10)/Al2O3. It is thought that this is because the surface Pt atoms on Ni catalyst can contribute to the enhancement of the catalyst reducibility.

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Authors and Affiliations

  1. Institute of Materials Science, University of Tsukuba, 1-1-1, Tennodai, Tsukuba, Ibaraki, 305-8573, Japan

    Keiichi Tomishige & Kimio Kunimori

  2. Department of Applied Chemistry, School of Engineering, The University of Tokyo, Bunkyo-ku, 7-3-1, Tokyo, 113-8656, Japan

    Shogo Kanazawa

  3. Natural Gas & Project Planning Department, Japan National Oil Corporation, 2-2-2, Uchisaiwaicho, Chiyoda-ku, Tokyo, 100-8511, Japan

    Motoki Sato

  4. Technology Research & Development Department, Petroleum Energy Center, 4-3-9, Toranomon, Minato-ku, Tokyo, 105-0001, Japan

    Kenji Ikushima

Authors
  1. Keiichi Tomishige
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  2. Shogo Kanazawa
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  3. Motoki Sato
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  4. Kenji Ikushima
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  5. Kimio Kunimori
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Tomishige, K., Kanazawa, S., Sato, M. et al. Catalyst Design of Pt-Modified Ni/Al2O3 Catalyst with Flat Temperature Profile in Methane Reforming with CO2 and O2 . Catalysis Letters 84, 69–74 (2002). https://doi.org/10.1023/A:1021076601653

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